TU Darmstadt / ULB / TUprints

Ultrasound‐Induced Adsorption of Acousto‐Responsive Microgels at Water–Oil Interface

Stock, Sebastian ; Mirau, Luca ; Rutsch, Matthias ; Wismath, Sonja ; Kupnik, Mario ; Klitzing, Regine von ; Rahimzadeh, Amin (2024)
Ultrasound‐Induced Adsorption of Acousto‐Responsive Microgels at Water–Oil Interface.
In: Advanced Science, 2024, 11 (5)
doi: 10.26083/tuprints-00027104
Article, Secondary publication, Publisher's Version

[img] Text
ADVS_ADVS7005.pdf
Copyright Information: CC BY 4.0 International - Creative Commons, Attribution.

Download (3MB)
[img] Text (Supplement)
advs7005-sup-0001-suppmat.pdf
Copyright Information: CC BY 4.0 International - Creative Commons, Attribution.

Download (2MB)
Item Type: Article
Type of entry: Secondary publication
Title: Ultrasound‐Induced Adsorption of Acousto‐Responsive Microgels at Water–Oil Interface
Language: English
Date: 19 June 2024
Place of Publication: Darmstadt
Year of primary publication: 2 February 2024
Place of primary publication: Weinheim
Publisher: Wiley-VCH
Journal or Publication Title: Advanced Science
Volume of the journal: 11
Issue Number: 5
Collation: 10 Seiten
DOI: 10.26083/tuprints-00027104
Corresponding Links:
Origin: Secondary publication DeepGreen
Abstract:

Ultrasonic mixing is a well‐established method to disperse and mix substances. However, the effects of ultrasound on dispersed soft particles as well as on their adsorption kinetics at interfaces remain unexplored. Ultrasound not only accelerates the movement of particles via acoustic streaming, but recent research indicates that it can also manipulate the interaction of soft particles with the surrounding liquid. In this study, it evaluates the adsorption kinetics of microgel at the water‐oil interface under the influence of ultrasound. It quantifies how acoustic streaming accelerates the reduction of interfacial tension. It uses high‐frequency and low‐amplitude ultrasound, which has no destructive effects. Furthermore, it discusses the ultrasound‐induced shrinking and thus interfacial rearrangement of the microgels, which plays a secondary but non‐negligible role on interfacial tension reduction. It shows that the decrease in interfacial tension due to the acoustic streaming is stronger for microgels with higher cross‐linker density. Moreover, it shows that ultrasound can induce a reversible decrease in interfacial tension due to the shrinkage of microgels at the interface. The presented results may lead to a better understanding in any field where ultrasonic waves meet soft particles, e.g., controlled destabilization in foams and emulsions or systems for drug release.

Uncontrolled Keywords: interfacial tension, microgels, ultrasound, water–oil interface
Identification Number: Artikel-ID: 2305395
Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-271040
Classification DDC: 500 Science and mathematics > 530 Physics
600 Technology, medicine, applied sciences > 621.3 Electrical engineering, electronics
Divisions: 18 Department of Electrical Engineering and Information Technology > Measurement and Sensor Technology
05 Department of Physics > Institute for Condensed Matter Physics > Soft Matter at Interfaces (SMI)
Date Deposited: 19 Jun 2024 12:34
Last Modified: 20 Jun 2024 13:13
SWORD Depositor: Deep Green
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/27104
PPN: 519260449
Export:
Actions (login required)
View Item View Item