Unravelling the mechanism of CO₂ activation over low-loaded Cu/CeO₂(111) catalysts using operando and transient spectroscopies

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Item Type:	Article
Type of entry:	Secondary publication
Title:	Unravelling the mechanism of CO₂ activation over low-loaded Cu/CeO₂(111) catalysts using operando and transient spectroscopies
Language:	English
Date:	24 April 2024
Place of Publication:	Darmstadt
Year of primary publication:	27 April 2023
Place of primary publication:	London
Publisher:	Royal Society of Chemistry
Journal or Publication Title:	Catalysis Science & Technology
Volume of the journal:	13
Issue Number:	10
DOI:	10.26083/tuprints-00026659
Corresponding Links:	Publisher-DOI
Origin:	Secondary publication service
Abstract:	Using operando Raman and UV-vis spectroscopy as well as transient IR spectroscopy, low-loaded Cu/CeO₂(111) catalysts were investigated with respect to their redox behavior and the importance of adsorbates for the reverse water–gas shift (rWGS) reaction. Here it is shown that of two possible mechanisms the redox mechanism is predominant over an associative one.
Status:	Publisher's Version
URN:	urn:nbn:de:tuda-tuprints-266597
Classification DDC:	500 Science and mathematics > 540 Chemistry
Divisions:	07 Department of Chemistry > Eduard Zintl-Institut > Physical Chemistry
Date Deposited:	24 Apr 2024 12:46
Last Modified:	30 Apr 2024 06:48
URI:	https://tuprints.ulb.tu-darmstadt.de/id/eprint/26659
PPN:	517556464
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