Zhang, Shan-Ting ; Vitrant, Guy ; Pernot, Etienne ; Jiménez, Carmen ; Muñoz-Rojas, David ; Bellet, Daniel (2024)
Hazy Al₂O₃-FTO Nanocomposites: A Comparative Study with FTO-Based Nanocomposites Integrating ZnO and S:TiO₂ Nanostructures.
In: Nanomaterials, 2018, 8 (6)
doi: 10.26083/tuprints-00016811
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Item Type: | Article |
---|---|
Type of entry: | Secondary publication |
Title: | Hazy Al₂O₃-FTO Nanocomposites: A Comparative Study with FTO-Based Nanocomposites Integrating ZnO and S:TiO₂ Nanostructures |
Language: | English |
Date: | 16 January 2024 |
Place of Publication: | Darmstadt |
Year of primary publication: | 2018 |
Place of primary publication: | Basel |
Publisher: | MDPI |
Journal or Publication Title: | Nanomaterials |
Volume of the journal: | 8 |
Issue Number: | 6 |
Collation: | 14 Seiten |
DOI: | 10.26083/tuprints-00016811 |
Corresponding Links: | |
Origin: | Secondary publication DeepGreen |
Abstract: | In this study, we report the use of Al₂O₃ nanoparticles in combination with fluorine doped tin oxide (F:SnO₂, aka FTO) thin films to form hazy Al₂O₃-FTO nanocomposites. In comparison to previously reported FTO-based nanocomposites integrating ZnO and sulfur doped TiO₂ (S:TiO₂) nanoparticles (i.e., ZnO-FTO and S:TiO₂-FTO nanocomposites), the newly developed Al₂O₃-FTO nanocomposites show medium haze factor HT of about 30%, while they exhibit the least loss in total transmittance Ttot. In addition, Al₂O₃-FTO nanocomposites present a low fraction of large-sized nanoparticle agglomerates with equivalent radius req > 1 μm; effectively 90% of the nanoparticle agglomerates show req < 750 nm. The smaller feature size in Al₂O₃-FTO nanocomposites, as compared to ZnO-FTO and S:TiO₂-FTO nanocomposites, makes them more suitable for applications that are sensitive to roughness and large-sized features. With the help of a simple optical model developed in this work, we have simulated the optical scattering by a single nanoparticle agglomerate characterized by bottom radius r₀, top radius r₁, and height h. It is found that r₀ is the main factor affecting the HT(λ), which indicates that the haze factor of Al₂O₃-FTO and related FTO nanocomposites is mainly determined by the total surface coverage of all the nanoparticle agglomerates present. |
Uncontrolled Keywords: | FTO, nanocomposite, Al₂O₃, haze factor, optical scattering, TCO |
Status: | Publisher's Version |
URN: | urn:nbn:de:tuda-tuprints-168115 |
Classification DDC: | 500 Science and mathematics > 540 Chemistry 600 Technology, medicine, applied sciences > 660 Chemical engineering |
Divisions: | 11 Department of Materials and Earth Sciences > Material Science > Electronic Structure of Materials (ESM) |
Date Deposited: | 16 Jan 2024 10:19 |
Last Modified: | 02 Apr 2024 11:03 |
SWORD Depositor: | Deep Green |
URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/16811 |
PPN: | 516679163 |
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