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Hazy Al₂O₃-FTO Nanocomposites: A Comparative Study with FTO-Based Nanocomposites Integrating ZnO and S:TiO₂ Nanostructures

Zhang, Shan-Ting ; Vitrant, Guy ; Pernot, Etienne ; Jiménez, Carmen ; Muñoz-Rojas, David ; Bellet, Daniel (2024)
Hazy Al₂O₃-FTO Nanocomposites: A Comparative Study with FTO-Based Nanocomposites Integrating ZnO and S:TiO₂ Nanostructures.
In: Nanomaterials, 2018, 8 (6)
doi: 10.26083/tuprints-00016811
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Item Type: Article
Type of entry: Secondary publication
Title: Hazy Al₂O₃-FTO Nanocomposites: A Comparative Study with FTO-Based Nanocomposites Integrating ZnO and S:TiO₂ Nanostructures
Language: English
Date: 16 January 2024
Place of Publication: Darmstadt
Year of primary publication: 2018
Place of primary publication: Basel
Publisher: MDPI
Journal or Publication Title: Nanomaterials
Volume of the journal: 8
Issue Number: 6
Collation: 14 Seiten
DOI: 10.26083/tuprints-00016811
Corresponding Links:
Origin: Secondary publication DeepGreen
Abstract:

In this study, we report the use of Al₂O₃ nanoparticles in combination with fluorine doped tin oxide (F:SnO₂, aka FTO) thin films to form hazy Al₂O₃-FTO nanocomposites. In comparison to previously reported FTO-based nanocomposites integrating ZnO and sulfur doped TiO₂ (S:TiO₂) nanoparticles (i.e., ZnO-FTO and S:TiO₂-FTO nanocomposites), the newly developed Al₂O₃-FTO nanocomposites show medium haze factor HT of about 30%, while they exhibit the least loss in total transmittance Ttot. In addition, Al₂O₃-FTO nanocomposites present a low fraction of large-sized nanoparticle agglomerates with equivalent radius req > 1 μm; effectively 90% of the nanoparticle agglomerates show req < 750 nm. The smaller feature size in Al₂O₃-FTO nanocomposites, as compared to ZnO-FTO and S:TiO₂-FTO nanocomposites, makes them more suitable for applications that are sensitive to roughness and large-sized features. With the help of a simple optical model developed in this work, we have simulated the optical scattering by a single nanoparticle agglomerate characterized by bottom radius r₀, top radius r₁, and height h. It is found that r₀ is the main factor affecting the HT(λ), which indicates that the haze factor of Al₂O₃-FTO and related FTO nanocomposites is mainly determined by the total surface coverage of all the nanoparticle agglomerates present.

Uncontrolled Keywords: FTO, nanocomposite, Al₂O₃, haze factor, optical scattering, TCO
Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-168115
Classification DDC: 500 Science and mathematics > 540 Chemistry
600 Technology, medicine, applied sciences > 660 Chemical engineering
Divisions: 11 Department of Materials and Earth Sciences > Material Science > Electronic Structure of Materials (ESM)
Date Deposited: 16 Jan 2024 10:19
Last Modified: 02 Apr 2024 11:03
SWORD Depositor: Deep Green
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/16811
PPN: 516679163
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