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Nanoscale core–shell structure and recrystallization of swift heavy ion tracks in SrTiO₃

Gupta, Ashish Kumar ; Zarkadoula, Eva ; Ziatdinov, Maxim ; Kalinin, Sergei V. ; Paduri, Vikas Reddy ; Hachtel, Jordan A. ; Zhang, Yanwen ; Trautmann, Christina ; Weber, William J. ; Sachan, Ritesh (2024)
Nanoscale core–shell structure and recrystallization of swift heavy ion tracks in SrTiO₃.
In: Nanoscale, 2024, 16 (30)
doi: 10.26083/tuprints-00027864
Article, Secondary publication, Publisher's Version

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Item Type: Article
Type of entry: Secondary publication
Title: Nanoscale core–shell structure and recrystallization of swift heavy ion tracks in SrTiO₃
Language: English
Date: 30 September 2024
Place of Publication: Darmstadt
Year of primary publication: 1 July 2024
Place of primary publication: Cambridge
Publisher: The Royal Society of Chemistry
Journal or Publication Title: Nanoscale
Volume of the journal: 16
Issue Number: 30
DOI: 10.26083/tuprints-00027864
Corresponding Links:
Origin: Secondary publication DeepGreen
Abstract:

It is widely accepted that the interaction of swift heavy ions with many complex oxides is predominantly governed by the electronic energy loss that gives rise to nanoscale amorphous ion tracks along the penetration direction. The question of how electronic excitation and electron–phonon coupling affect the atomic system through defect production, recrystallization, and strain effects has not yet been fully clarified. To advance the knowledge of the atomic structure of ion tracks, we irradiated single crystalline SrTiO₃ with 629 MeV Xe ions and performed comprehensive electron microscopy investigations complemented by molecular dynamics simulations. This study shows discontinuous ion-track formation along the ion penetration path, comprising an amorphous core and a surrounding few monolayer thick shell of strained/defective crystalline SrTiO₃. Using machine-learning-aided analysis of atomic-scale images, we demonstrate the presence of 4–8% strain in the disordered region interfacing with the amorphous core in the initially formed ion tracks. Under constant exposure of the electron beam during imaging, the amorphous part of the ion tracks readily recrystallizes radially inwards from the crystalline-amorphous interface under the constant electron-beam irradiation during the imaging. Cation strain in the amorphous region is observed to be significantly recovered, while the oxygen sublattice remains strained even under the electron irradiation due to the present oxygen vacancies. The molecular dynamics simulations support this observation and suggest that local transient heating and annealing facilitate recrystallization process of the amorphous phase and drive Sr and Ti sublattices to rearrange. In contrast, the annealing of O atoms is difficult, thus leaving a remnant of oxygen vacancies and strain even after recrystallization. This work provides insights for creating and transforming novel interfaces and nanostructures for future functional applications.

Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-278649
Classification DDC: 500 Science and mathematics > 530 Physics
500 Science and mathematics > 540 Chemistry
Divisions: 11 Department of Materials and Earth Sciences > Material Science > Ion-Beam-Modified Materials
Date Deposited: 30 Sep 2024 12:28
Last Modified: 24 Oct 2024 09:19
SWORD Depositor: Deep Green
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/27864
PPN: 522428592
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