Stowasser, Bernd ; Hafner, Klaus (2023)
Synthesis of a Dicyclopenta[a, e]pentalene by [6 + 2]-Cycloaddition of 1,3-Di-tert-butyl-5-vinylidenecyclopentadiene and Consecutive 8π-Electrocyclic Reaction.
In: Angewandte Chemie International Edition, 1986, 25 (5)
doi: 10.26083/tuprints-00022360
Article, Secondary publication, Publisher's Version
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Angew Chem Int Ed Engl - May 1986 - Stowasser - Synthesis of a Dicyclopenta a e pentalene by 6 2 ‐Cycloaddition of.pdf Copyright Information: In Copyright. Download (943kB) |
| Item Type: | Article |
|---|---|
| Type of entry: | Secondary publication |
| Title: | Synthesis of a Dicyclopenta[a, e]pentalene by [6 + 2]-Cycloaddition of 1,3-Di-tert-butyl-5-vinylidenecyclopentadiene and Consecutive 8π-Electrocyclic Reaction |
| Language: | English |
| Date: | 2023 |
| Place of Publication: | Darmstadt |
| Year of primary publication: | 1986 |
| Publisher: | Wiley |
| Journal or Publication Title: | Angewandte Chemie International Edition |
| Volume of the journal: | 25 |
| Issue Number: | 5 |
| DOI: | 10.26083/tuprints-00022360 |
| Corresponding Links: | |
| Origin: | Secondary publication service |
| Abstract: | The first non-benzenoid, linearly annelated, tetracyclic system with [4n + 2]-perimeter and [4n]-partial structures was obtained by dimerization of the allene derivative 1 via [6 + 2]-cycloaddition. Subsequent 8π-electrocyclization yielded a tetraquinane, which could be dehydrogenated to the title compound 2. |
| Status: | Publisher's Version |
| URN: | urn:nbn:de:tuda-tuprints-223603 |
| Classification DDC: | 500 Science and mathematics > 540 Chemistry |
| Divisions: | 07 Department of Chemistry > Clemens-Schöpf-Institut > Organ Chemistry |
| Date Deposited: | 28 Feb 2023 08:47 |
| Last Modified: | 18 Aug 2023 06:33 |
| URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/22360 |
| PPN: | 510686605 |
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