Synthesis, Reactions and Properties of Iron, Cobalt and Nickel Complexes Containing some [P,S]-chelating Ligands and Trimethylphosphine

Bennour, Hamdi (2010)
Synthesis, Reactions and Properties of Iron, Cobalt and Nickel Complexes Containing some [P,S]-chelating Ligands and Trimethylphosphine.
Technische Universität Darmstadt
Ph.D. Thesis, Primary publication

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Item Type:

Ph.D. Thesis

Type of entry:

Primary publication

Title:

Synthesis, Reactions and Properties of Iron, Cobalt and Nickel Complexes Containing some [P,S]-chelating Ligands and Trimethylphosphine

Language:

English

Referees:

Klein, Prof. Dr. H.-F. ; Schneider, Prof. Dr. J. J.

Date:

26 March 2010

Place of Publication:

Darmstadt

Date of oral examination:

8 February 2010

Abstract:

The work submitted here is concerned with the synthesis and characterization of new [P,S]-chelate complexes of the iron, cobalt and nickel, supported by trimethylphosphine ligands and with an investigation of chemical responses of these systems. Among the new compounds of these metals are stable hydrido and methyl metal compounds in low and high oxidation states which are of particular interest as models for homogeneous catalysis.

Alternative Abstract:

Alternative Abstract

Language

Die hier vorgelegte Arbeit beschreibt Synthesen und Charakterisierung neuer [P,S]-chelate von Eisen, Cobalt und Nickel, die von Trimethylphosphin-Liganden gestützt werden, und die Untersuchung der chemischen Eigenschaften dieser Systeme. Unter den neuen Verbindungen ragen stabile Hydrido- und Methylmetall-Komplexe in hohen und niedrigen Oxidationsstufen heraus, die als Modellverbindungen für die Homogene Katalyse von besonderem Interesse sind.

German

Uncontrolled Keywords:

Synthesis, Iron, Cobalt, Nickel, Complex, Trimethylphosphine

Alternative keywords: