Kumar, Sandeep ; Pramudya, Yohanes ; Müller, Kai ; Chandresh, Abhinav ; Dehm, Simone ; Heidrich, Shahriar ; Fediai, Artem ; Parmar, Devang ; Perera, Delwin ; Rommel, Manuel ; Heinke, Lars ; Wenzel, Wolfgang ; Wöll, Christof ; Krupke, Ralph (2023)
Sensing Molecules with Metal–Organic Framework Functionalized Graphene Transistors.
In: Advanced Materials, 2021, 33 (43)
doi: 10.26083/tuprints-00021004
Article, Secondary publication, Publisher's Version
Text
ADMA_ADMA202103316.pdf Copyright Information: CC BY 4.0 International - Creative Commons, Attribution. Download (4MB) |
|
Text
(Supplement)
adma202103316-sup-0001-suppmat.pdf Copyright Information: CC BY 4.0 International - Creative Commons, Attribution. Download (3MB) |
Item Type: | Article |
---|---|
Type of entry: | Secondary publication |
Title: | Sensing Molecules with Metal–Organic Framework Functionalized Graphene Transistors |
Language: | English |
Date: | 11 December 2023 |
Place of Publication: | Darmstadt |
Year of primary publication: | 2021 |
Place of primary publication: | Weinheim |
Publisher: | Wiley-VCH |
Journal or Publication Title: | Advanced Materials |
Volume of the journal: | 33 |
Issue Number: | 43 |
Collation: | 12 Seiten |
DOI: | 10.26083/tuprints-00021004 |
Corresponding Links: | |
Origin: | Secondary publication DeepGreen |
Abstract: | Graphene is inherently sensitive to vicinal dielectrics and local charge distributions, a property that can be probed by the position of the Dirac point in graphene field‐effect transistors. Exploiting this as a useful sensing principle requires selectivity; however, graphene itself exhibits no molecule‐specific interaction. Complementarily, metal–organic frameworks can be tailored to selective adsorption of specific molecular species. Here, a selective ethanol sensor is demonstrated by growing a surface‐mounted metal–organic framework (SURMOF) directly onto graphene field‐effect transistors (GFETs). Unprecedented shifts of the Dirac point, as large as 15 V, are observed when the SURMOF/GFET is exposed to ethanol, while a vanishingly small response is observed for isopropanol, methanol, and other constituents of the air, including water. The synthesis and conditioning of the hybrid materials sensor with its functional characteristics are described and a model is proposed to explain the origin, magnitude, and direction of the Dirac point voltage shift. Tailoring multiple SURMOFs to adsorb specific gases on an array of such devices thus generates a versatile, selective, and highly sensitive platform for sensing applications. |
Uncontrolled Keywords: | alcohol, graphene, metal–organic frameworks, sensing, transistors |
Identification Number: | 2103316 |
Status: | Publisher's Version |
URN: | urn:nbn:de:tuda-tuprints-210047 |
Classification DDC: | 500 Science and mathematics > 540 Chemistry 600 Technology, medicine, applied sciences > 660 Chemical engineering |
Divisions: | 11 Department of Materials and Earth Sciences > Material Science > Materials Modelling 11 Department of Materials and Earth Sciences > Material Science > Molecular Nanostructures |
Date Deposited: | 11 Dec 2023 13:56 |
Last Modified: | 23 Feb 2024 07:20 |
SWORD Depositor: | Deep Green |
URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/21004 |
PPN: | 515639117 |
Export: |
View Item |