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The material behavior of asphalt depends on its composition of aggregate, bitumen, and air voids. Asphalt pavements consist of multiple layers, making the interaction of the materials at the layer boundary important so that any stresses that occur can be relieved. The material behavior at the layer boundary is not yet understood in detail, as further methods of analysis are lacking in addition to mechanical methods. For this reason, the layer boundary of asphalt structures was analyzed using imaging methods. The aim of this research was to find an imaging method that allows a detailed analysis of the bonding zone of asphalt layers. Two different imaging techniques were used for this purpose. One is a 2-D imaging technique (asphalt petrology) and the other is a 3-D imaging technique (high-resolution computed tomography). Image analysis is a widely used technique in materials science that allows to analyze the material behavior and their composition. In this research, attention was paid to the analysis of the position of the bitumen emulsion, because the contained bitumen is supposed to bond the layers together. It was found that the application of 2-D imaging (asphalt petrology) lacked the precision for a detailed analysis of the individual materials at the layer boundary. With high-resolution computed tomography, a detailed view is possible to visualize the individual materials at the layer boundary in 3D. However, it is difficult to differentiate the materials because there are no gradations in the gray values due to the identical densities. However, it is possible to differentiate between the bitumen from the asphalt and from the emulsion if a high-density tracer is added to the bitumen emulsion for the CT studies. The results of the investigations are presented in this article.