Tom, Jessica C. ; Appel, Christian ; Andrieu-Brunsen, Annette (2021)
Fabrication and in situ functionalisation of mesoporous silica films by the physical entrapment of functional and responsive block copolymer structuring agents.
In: Soft Matter, 2021, 15 (40)
doi: 10.26083/tuprints-00019781
Article, Secondary publication, Postprint
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| Item Type: | Article |
|---|---|
| Type of entry: | Secondary publication |
| Title: | Fabrication and in situ functionalisation of mesoporous silica films by the physical entrapment of functional and responsive block copolymer structuring agents |
| Language: | English |
| Date: | 2021 |
| Place of Publication: | Darmstadt |
| Year of primary publication: | 2021 |
| Publisher: | Royal Society of Chemistry (RSC) |
| Journal or Publication Title: | Soft Matter |
| Volume of the journal: | 15 |
| Issue Number: | 40 |
| Collation: | 10 ungezählte Seiten |
| DOI: | 10.26083/tuprints-00019781 |
| Corresponding Links: | |
| Origin: | Secondary publication service |
| Abstract: | Stimuli-responsive mesoporous silica films were prepared by evaporation-induced self-assembly through the physical entrapment of a functional block copolymer structuring agent, which simultaneously serves to functionalise the mesopore. These polymer–silica hybrid materials exhibit remarkable ionic permselectivity under highly filled conditions, and offer the potential for local polymer functionalisation for enhanced and tunable ionic permselectivity. This innovative and simple approach for the in situ functionalisation of mesoporous silica has the potential to improve how we approach the design of complex architectures at the nanoscale for enhanced transport, and is thus relevant for a variety of technologies based on molecular transport in nanoscale pores including separation, sensing, catalysis, and energy conversion. |
| Status: | Postprint |
| URN: | urn:nbn:de:tuda-tuprints-197815 |
| Additional Information: | Supplement vorhanden (20 Seiten) |
| Classification DDC: | 500 Science and mathematics > 540 Chemistry |
| Divisions: | Profile Areas > Thermo-Fluids & Interfaces 07 Department of Chemistry > Ernst-Berl-Institut > Fachgebiet Makromolekulare Chemie |
| Date Deposited: | 28 Oct 2021 12:07 |
| Last Modified: | 09 Jan 2023 08:15 |
| URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/19781 |
| PPN: | 503405337 |
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