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Indentation densification of fused silica assessed by raman spectroscopy and constitutive finite element analysis

Bruns, Sebastian ; Uesbeck, Tobias ; Fuhrmann, Sindy ; Tarragó Aymerich, Mariona ; Wondraczek, Lothar ; Ligny, Dominique de ; Durst, Karsten (2024)
Indentation densification of fused silica assessed by raman spectroscopy and constitutive finite element analysis.
In: Journal of the American Ceramic Society, 2020, 103 (5)
doi: 10.26083/tuprints-00015639
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Item Type: Article
Type of entry: Secondary publication
Title: Indentation densification of fused silica assessed by raman spectroscopy and constitutive finite element analysis
Language: English
Date: 9 January 2024
Place of Publication: Darmstadt
Year of primary publication: 2020
Place of primary publication: Oxford
Publisher: Wiley-Blackwell
Journal or Publication Title: Journal of the American Ceramic Society
Volume of the journal: 103
Issue Number: 5
DOI: 10.26083/tuprints-00015639
Corresponding Links:
Origin: Secondary publication DeepGreen
Abstract:

Inelastic deformation of anomalous glasses manifests in shear flow and densification of the glass network; the deformation behavior during indentation testing is linked strongly to both processes. In this paper, the indentation densification field of fused silica is investigated using depth‐resolved Raman spectroscopy and finite element simulations. Through affecting the size of the indent, the normal load and the Raman laser spot size determine the spatial sampling resolution, leading to a certain degree of structural averaging. For appropriate combinations of normal load (indent size) and laser spot diameter, a maximum densification of 18.4% was found at the indent center. The indentation behavior was modeled by extended Drucker‐Prager‐Cap (DPC) plasticity, assuming a sigmoidal hardening behavior of fused silica with a densification saturation of 21%. This procedure significantly improved the reproduction of the experimental densification field, yielding a maximum densification of 18.2% directly below the indenter tip. The degree of densification was found to be strongly linked to the hydrostatic pressure limit below the indenter in accordance to Johnson's expanding cavity model (J. Mech. Phys. Solids, 18 (1970) 115). Based on the good overlap between FEA and Raman, an alternative way to extract the empirical correlation factor m, which scales structural densification to Raman spectroscopic observations, is obtained. This approach does not require the use of intensive hydrostatic compaction experiments.

Uncontrolled Keywords: densification, drucker‐prager‐cap plasticity, finite element analysis, fused silica, indentation, Raman Spectroscopy
Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-156396
Classification DDC: 500 Science and mathematics > 540 Chemistry
600 Technology, medicine, applied sciences > 660 Chemical engineering
Divisions: 11 Department of Materials and Earth Sciences > Material Science > Physical Metallurgy
Date Deposited: 09 Jan 2024 12:43
Last Modified: 12 Jan 2024 08:14
SWORD Depositor: Deep Green
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/15639
PPN: 514629037
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