Frebel, Alexander ; Yoon, Songhak ; Neguse, Samuel Meles ; Jöckel, Dennis Michael ; Widenmeyer, Marc ; Ebbinghaus, Stefan G. ; Balke‐Grünewald, Benjamin ; Weidenkaff, Anke (2024)
Morphologically and Compositionally Controlled Cs₂SbBr₆ by Bi and Ag Substitution.
In: Crystal Research and Technology, 2024, 59 (10)
doi: 10.26083/tuprints-00028277
Article, Secondary publication, Publisher's Version
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| Item Type: | Article |
|---|---|
| Type of entry: | Secondary publication |
| Title: | Morphologically and Compositionally Controlled Cs₂SbBr₆ by Bi and Ag Substitution |
| Language: | English |
| Date: | 19 November 2024 |
| Place of Publication: | Darmstadt |
| Year of primary publication: | October 2024 |
| Place of primary publication: | Weinheim |
| Publisher: | Wiley-VCH |
| Journal or Publication Title: | Crystal Research and Technology |
| Volume of the journal: | 59 |
| Issue Number: | 10 |
| Collation: | 7 Seiten |
| DOI: | 10.26083/tuprints-00028277 |
| Corresponding Links: | |
| Origin: | Secondary publication DeepGreen |
| Abstract: | Morphology‐controlled Cs₂SbBr₆ crystals are synthesized by Bi‐ and Ag‐substitution of the precursor solution. X‐ray diffraction (XRD) together with Raman spectroscopy confirms the lattice tilting and symmetry changes with the dominant appearance of higher index facets by Bi substitution. Ag substitution does not induce crystal symmetry changes in the Cs₂SbBr₆ (B = Sb or Bi) phase, but results in highly defective structures hindering the formation of a smooth surface during the crystal growth. Successful substitution of Bi and limited substitution of Ag into Cs₂SbBr₆ is also confirmed by energy dispersive X‐ray spectroscopy (EDX). This research provides design principles and practical examples of how to control the morphology of Cs₂SbBr₆ crystals with structural defects and multiphase formation. |
| Uncontrolled Keywords: | Cs₂SbBr₆, Cs₃Sb₂Br₉, Morphology change, Oriented attachment, Raman spectroscopy, X‐ray diffraction |
| Identification Number: | Artikel-ID: 2400055 |
| Status: | Publisher's Version |
| URN: | urn:nbn:de:tuda-tuprints-282775 |
| Classification DDC: | 500 Science and mathematics > 530 Physics 500 Science and mathematics > 540 Chemistry 600 Technology, medicine, applied sciences > 660 Chemical engineering |
| Divisions: | 11 Department of Materials and Earth Sciences > Material Science > Materials and Resources |
| Date Deposited: | 19 Nov 2024 12:22 |
| Last Modified: | 02 Dec 2024 10:20 |
| SWORD Depositor: | Deep Green |
| URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/28277 |
| PPN: | 524288704 |
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