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Mapping humidity-dependent mechanical properties of a single cellulose fibre

Auernhammer, Julia ; Keil, Tom ; Lin, Binbin ; Schäfer, Jan-Lukas ; Xu, Bai-Xiang ; Biesalski, Markus ; Stark, Robert W. (2024)
Mapping humidity-dependent mechanical properties of a single cellulose fibre.
In: Cellulose, 2021, 28 (13)
doi: 10.26083/tuprints-00023522
Article, Secondary publication, Publisher's Version

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Item Type: Article
Type of entry: Secondary publication
Title: Mapping humidity-dependent mechanical properties of a single cellulose fibre
Language: English
Date: 10 December 2024
Place of Publication: Darmstadt
Year of primary publication: September 2021
Place of primary publication: Dordrecht
Publisher: Springer Science
Journal or Publication Title: Cellulose
Volume of the journal: 28
Issue Number: 13
DOI: 10.26083/tuprints-00023522
Corresponding Links:
Origin: Secondary publication DeepGreen
Abstract:

Modelling of single cellulose fibres is usually performed by assuming homogenous properties, such as strength and Young’s modulus, for the whole fibre. Additionally, the inhomogeneity in size and swelling behaviour along the fibre is often disregarded. For better numerical models, a more detailed characterisation of the fibre is required. Herein, we report a method based on atomic force microscopy to map these properties along the fibre. A fibre was mechanically characterised by static colloidal probe AFM measurements along the longitudinal direction of the fibre. Thus, the contact stress and strain at each loading point could be extracted. Stress–strain curves were be obtained along the fibre. Additionally, mechanical properties such as adhesion or dissipation were mapped. Local variations of the effective fibre radius were recorded via confocal laser scanning microscopy. Scanning electron microscopy measurements revealed the local macroscopic fibril orientation and provided an overview of the fibre topography. By combining these data, regions along the fibre with higher adhesion, dissipation, bending ability and strain or differences in the contact stress when increasing the relative humidity could be identified. This combined approach allows for one to obtain a detailed picture of the mechanical properties of single fibres.

Uncontrolled Keywords: Cellulose, Single Fibre Strength, Scanning Electron Microscopy, Confocal Laser Scanning Microscopy, Atomic Force Microscopy, Colloidal Probe
Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-235228
Classification DDC: 500 Science and mathematics > 530 Physics
500 Science and mathematics > 540 Chemistry
Divisions: 11 Department of Materials and Earth Sciences > Material Science > Mechanics of functional Materials
11 Department of Materials and Earth Sciences > Material Science > Physical Metallurgy
11 Department of Materials and Earth Sciences > Material Science > Physics of Surfaces
07 Department of Chemistry > Ernst-Berl-Institut > Fachgebiet Makromolekulare Chemie > Macromolecular and paper chemistry
Date Deposited: 10 Dec 2024 13:07
Last Modified: 18 Dec 2024 12:09
SWORD Depositor: Deep Green
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/23522
PPN: 524643210
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