Ren, Pengrong ; Höfling, Marion ; Koruza, Jurij ; Lauterbach, Stefan ; Jiang, Xijie ; Frömling, Till ; Khatua, Dipak Kumar ; Dietz, Christian ; Porz, Lukas ; Ranjan, Rajeev ; Kleebe, Hans‐Joachim ; Rödel, Jürgen (2023)
High temperature creep‐mediated functionality in polycrystalline barium titanate.
In: Journal of the American Ceramic Society, 2019, 103 (3)
doi: 10.26083/tuprints-00023203
Article, Secondary publication, Publisher's Version
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Item Type: | Article |
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Type of entry: | Secondary publication |
Title: | High temperature creep‐mediated functionality in polycrystalline barium titanate |
Language: | English |
Date: | 2023 |
Place of Publication: | Darmstadt |
Year of primary publication: | 2019 |
Publisher: | Wiley |
Journal or Publication Title: | Journal of the American Ceramic Society |
Volume of the journal: | 103 |
Issue Number: | 3 |
DOI: | 10.26083/tuprints-00023203 |
Corresponding Links: | |
Origin: | Secondary publication service |
Abstract: | Dislocations in oxides can be described as charged line defects and means for one-dimensional doping, which can tune electrical and thermal properties. Furthermore, theoretically it was shown that dislocations can pin ferroelectric domain walls. Broader application of this concept hinges on the development of a methodology to avail this approach to polycrystalline ceramics. To this end, we use different creep mechanisms as a method to introduce multidimensional defects and quantify structural changes. A deformation map for fine-grained barium titanate is provided and the influences of the defects and creep regimes are correlated in this first study to modifications of electrical conductivity, dielectric, ferroelectric, and piezoelectric properties. A plastic deformation of 1.29% resulted in an increase in the Curie temperature by 5°C and a decrease in electromechanical strain by 30%, pointing toward electromechanical hardening by dislocations. |
Uncontrolled Keywords: | barium titanate, creep, dislocations, ferroelectricity/ferroelectric materials, piezoelectric materials/ properties |
Status: | Publisher's Version |
URN: | urn:nbn:de:tuda-tuprints-232035 |
Classification DDC: | 500 Science and mathematics > 530 Physics 500 Science and mathematics > 540 Chemistry |
Divisions: | 11 Department of Materials and Earth Sciences > Material Science > Nonmetallic-Inorganic Materials 11 Department of Materials and Earth Sciences > Material Science > Physics of Surfaces |
Date Deposited: | 10 Feb 2023 09:26 |
Last Modified: | 25 May 2023 06:13 |
URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/23203 |
PPN: | 507931386 |
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