Neuenschwander, M. ; Hafner, Klaus (2023)
A New Rearrangement of Substituted 3-Aminopropenals.
In: Angewandte Chemie International Edition, 1968, 7 (6)
doi: 10.26083/tuprints-00022285
Article, Secondary publication, Publisher's Version
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Angew Chem Int Ed Engl - June 1968 - Neuenschwander - A New Rearrangement of Substituted 3‐Aminopropenals.pdf Copyright Information: In Copyright. Download (713kB) |
| Item Type: | Article |
|---|---|
| Type of entry: | Secondary publication |
| Title: | A New Rearrangement of Substituted 3-Aminopropenals |
| Language: | English |
| Date: | 2023 |
| Place of Publication: | Darmstadt |
| Year of primary publication: | 1968 |
| Publisher: | Wiley |
| Journal or Publication Title: | Angewandte Chemie International Edition |
| Volume of the journal: | 7 |
| Issue Number: | 6 |
| DOI: | 10.26083/tuprints-00022285 |
| Corresponding Links: | |
| Origin: | Secondary publication service |
| Abstract: | 3-(Dimethylamino)prop-2-yn-1-al (1) reacts with an equimolar quantity of HCl in anhydrous tetrahydrofuran at 0 °C to give the reactive aldehyde (2), R = Cl [¹], which rearranges during isolation to form isomer-free[²] trans-3-chloro-N,N-dimethylacrylamide (3a), R = Cl (yield 80 %) [³]. |
| Status: | Publisher's Version |
| URN: | urn:nbn:de:tuda-tuprints-222855 |
| Classification DDC: | 500 Science and mathematics > 540 Chemistry |
| Divisions: | 07 Department of Chemistry > Clemens-Schöpf-Institut > Organ Chemistry |
| Date Deposited: | 21 Mar 2023 10:38 |
| Last Modified: | 18 Aug 2023 06:18 |
| URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/22285 |
| PPN: | 510685463 |
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