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Sub-micrometer refractory carbonaceous particles in the polar stratosphere

Schütze, Katharina ; Wilson, James Charles ; Weinbruch, Stephan ; Benker, Nathalie ; Ebert, Martin ; Günther, Gebhard ; Weigel, Ralf ; Borrmann, Stephan (2017):
Sub-micrometer refractory carbonaceous particles in the polar stratosphere.
17, In: Atmospheric Chemistry and Physics, (20), pp. 12475-12493. Copernicus, ISSN 1680-7324,
DOI: 10.5194/acp-17-12475-2017,
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Item Type: Article
Origin: Secondary publication via sponsored Golden Open Access
Title: Sub-micrometer refractory carbonaceous particles in the polar stratosphere
Language: English
Abstract:

Eleven particle samples collected in the polar stratosphere during SOLVE (SAGE III Ozone loss and validation experiment) from January until March 2000 were characterized in detail by high-resolution transmission and scanning electron microscopy (TEM/SEM) combined with energy-dispersive X-ray microanalysis. A total of 4202 particles (TEM = 3872; SEM = 330) were analyzed from these samples, which were collected mostly inside the polar vortex in the altitude range between 17.3 and 19.9 km. Particles that were volatile in the microscope beams contained ammonium sulfates and hydrogen sulfates and dominated the samples. Some particles with diameters ranging from 20 to 830 nm were refractory in the electron beams. Carbonaceous particles containing additional elements to C and O comprised from 72 to 100 % of the refractory particles. The rest were internal mixtures of these materials with sulfates. The median number mixing ratio of the refractory particles, expressed in units of particles per milligram of air, was 1.1 (mg air)−1 and varied between 0.65 and 2.3 (mg air)−1. Most of the refractory carbonaceous particles are completely amorphous, a few of the particles are partly ordered with a graphene sheet separation distance of 0.37 ± 0.06 nm (mean value ± standard eviation). Carbon and oxygen are the only detected major elements with an atomic O/C ratio of 0.11 ± 0.07. Minor elements observed include Si, S, Fe, Cr and Ni with the following atomic ratios relative to C: Si/C: 0.010 ± 0.011; S/C: 0.0007 ± 0.0015; Fe/C: 0.0052 ± 0.0074; Cr/C: 0.0012 ± 0.0017; Ni/C: 0.0006 ± 0.0011 (all mean values ± standard deviation). High-resolution element distribution images reveal that the minor elements are distributed within the arbonaceous matrix; i.e., heterogeneous inclusions are not observed. No difference in size, nanostructure and elemental composition was found between particles collected inside and outside the polar vortex. Based on chemistry and nanostructure, aircraft exhaust, volcanic missions and biomass burning can certainly be excluded as sources. The same is true for the less probable but globally important sources: wood burning, coal burning, diesel engines and ship emissions. Recondensed organic matter and extraterrestrial particles, potentially originating from ablation and fragmentation, remain as possible sources of the refractory carbonaceous particles studied. However, additional work is required in order to identify the sources unequivocally.

Journal or Publication Title: Atmospheric Chemistry and Physics
Series Volume: 17
Issue Number: 20
Publisher: Copernicus
Classification DDC: 500 Naturwissenschaften und Mathematik > 550 Geowissenschaften
Divisions: 11 Department of Materials and Earth Sciences > Earth Science
Date Deposited: 01 Nov 2017 13:47
Last Modified: 09 Jul 2020 01:54
DOI: 10.5194/acp-17-12475-2017
URN: urn:nbn:de:tuda-tuprints-69295
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/6929
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