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Toward Renewable Amines: Recent Advances in the Catalytic Amination of Biomass-Derived Oxygenates

Gupta, Navneet Kumar ; Reif, Phillip ; Palenicek, Phillip ; Rose, Marcus (2023)
Toward Renewable Amines: Recent Advances in the Catalytic Amination of Biomass-Derived Oxygenates.
In: ACS Catalysis, 2022, 12 (16)
doi: 10.26083/tuprints-00024525
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Item Type: Article
Type of entry: Secondary publication
Title: Toward Renewable Amines: Recent Advances in the Catalytic Amination of Biomass-Derived Oxygenates
Language: English
Date: 20 November 2023
Place of Publication: Darmstadt
Year of primary publication: 19 August 2022
Place of primary publication: Washington, DC, USA
Publisher: American Chemical Society
Journal or Publication Title: ACS Catalysis
Volume of the journal: 12
Issue Number: 16
DOI: 10.26083/tuprints-00024525
Corresponding Links:
Origin: Secondary publication service

Synthesis of high-value-added chemicals from biomass and/or biomass-derived platform molecules is considered an important strategy to mitigate the global dependency on fossil resources and include renewable resources in a circular economy. In recent years, the synthesis of bio-based plastics has received significant attention as a potential alternative to conventional industrial processes. Thus, a lot of effort has been put into the development of not only different classes of biomonomers but also bio-based drop-in chemicals. Amine-derived molecules, especially alcohol-amines, diamines, and N-heterocyclic amines, are the most important classes of functional monomers for the production of polyamides, polyimides, polyurethanes, and polyureas. Additionally, these amines are extensively used in pharmaceuticals. In this review, we will give a concise overview of the up-to-date methods for the production of industrially important amines from biomass-derived oxygenates. Special attention will be given to the catalytic amination of biomass aldehyde- and alcohol-based oxygenates, reaction mechanism, catalyst stability, as well as their specific challenges and opportunities. We anticipate this critical and comprehensive review to provide detailed insights into the synthesis of bio-based amines and guide the development of effective greener synthetic methodologies.

Uncontrolled Keywords: Biomass, diamines, sustainable chemistry, catalysis, amination, diol, oxygenates
Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-245255
Classification DDC: 500 Science and mathematics > 540 Chemistry
Divisions: 07 Department of Chemistry > Ernst-Berl-Institut > Fachgebiet Technische Chemie
Date Deposited: 20 Nov 2023 11:09
Last Modified: 27 Nov 2023 07:19
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/24525
PPN: 513470573
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