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Accessibility of fiber surface sites for polymeric additives determines dry and wet tensile strength of paper sheets

Schäfer, J.-L. ; Schölch, S. ; Prucker, O. ; Brandstetter, T. ; Rühe, J. ; Stockert, A. Ritter v. ; Meckel, T. ; Biesalski, M. (2024)
Accessibility of fiber surface sites for polymeric additives determines dry and wet tensile strength of paper sheets.
In: Cellulose, 2021, 28 (9)
doi: 10.26083/tuprints-00023523
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Item Type: Article
Type of entry: Secondary publication
Title: Accessibility of fiber surface sites for polymeric additives determines dry and wet tensile strength of paper sheets
Language: English
Date: 10 December 2024
Place of Publication: Darmstadt
Year of primary publication: June 2021
Place of primary publication: Dordrecht
Publisher: Springer Science
Journal or Publication Title: Cellulose
Volume of the journal: 28
Issue Number: 9
DOI: 10.26083/tuprints-00023523
Corresponding Links:
Origin: Secondary publication DeepGreen
Abstract:

This contribution focuses on understanding of paper wet-strength properties, by taking a closer look at the spatial distribution of wet-strengthening polymers inside the cellulosic fiber network deposited under different treatment conditions using confocal laser scanning microscopy as in situ imaging tool. We compare the behavior of paper samples treated with a photochemically cross-linkable copolymer using an impregnation process employing three different solvents, namely water, 2-propanol (IPA) and 1-butanol (BuOH), respectively. As these solvents swell paper fibers to quite different extents, the deposition of the polymer, on, in or in-between the cellulosic fibers varies quite strongly, as is shown by in-depth analysis using confocal laser scanning microscopy. The difference in accessibility of distinct surface sites exclusively on or also in and between the fibers controls the macroscopic tensile strength under both dry and wet conditions.

Uncontrolled Keywords: Cellulose, Paper, Wet strength, Spatial distribution, Swelling, Photo-crosslinking
Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-235232
Classification DDC: 500 Science and mathematics > 540 Chemistry
Divisions: 07 Department of Chemistry > Ernst-Berl-Institut > Fachgebiet Makromolekulare Chemie > Macromolecular and paper chemistry
Date Deposited: 10 Dec 2024 13:11
Last Modified: 13 Dec 2024 10:53
SWORD Depositor: Deep Green
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/23523
PPN: 524554161
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