Schäfer, J.-L. ; Schölch, S. ; Prucker, O. ; Brandstetter, T. ; Rühe, J. ; Stockert, A. Ritter v. ; Meckel, T. ; Biesalski, M. (2024)
Accessibility of fiber surface sites for polymeric additives determines dry and wet tensile strength of paper sheets.
In: Cellulose, 2021, 28 (9)
doi: 10.26083/tuprints-00023523
Article, Secondary publication, Publisher's Version
Text
s10570-021-03817-7.pdf Copyright Information: CC BY 4.0 International - Creative Commons, Attribution. Download (2MB) |
|
Text
(Supplement)
10570_2021_3817_MOESM1_ESM.pdf Copyright Information: CC BY 4.0 International - Creative Commons, Attribution. Download (6MB) |
|
Video
(Supplement)
Accessibility of fiber surface sites for polymeric additives-2.mp4 Copyright Information: CC BY 4.0 International - Creative Commons, Attribution. Download (154kB) |
|
Video
(Supplement)
Accessibility of fiber surface sites for polymeric additives-3.mp4 Copyright Information: CC BY 4.0 International - Creative Commons, Attribution. Download (344kB) |
Item Type: | Article |
---|---|
Type of entry: | Secondary publication |
Title: | Accessibility of fiber surface sites for polymeric additives determines dry and wet tensile strength of paper sheets |
Language: | English |
Date: | 10 December 2024 |
Place of Publication: | Darmstadt |
Year of primary publication: | June 2021 |
Place of primary publication: | Dordrecht |
Publisher: | Springer Science |
Journal or Publication Title: | Cellulose |
Volume of the journal: | 28 |
Issue Number: | 9 |
DOI: | 10.26083/tuprints-00023523 |
Corresponding Links: | |
Origin: | Secondary publication DeepGreen |
Abstract: | This contribution focuses on understanding of paper wet-strength properties, by taking a closer look at the spatial distribution of wet-strengthening polymers inside the cellulosic fiber network deposited under different treatment conditions using confocal laser scanning microscopy as in situ imaging tool. We compare the behavior of paper samples treated with a photochemically cross-linkable copolymer using an impregnation process employing three different solvents, namely water, 2-propanol (IPA) and 1-butanol (BuOH), respectively. As these solvents swell paper fibers to quite different extents, the deposition of the polymer, on, in or in-between the cellulosic fibers varies quite strongly, as is shown by in-depth analysis using confocal laser scanning microscopy. The difference in accessibility of distinct surface sites exclusively on or also in and between the fibers controls the macroscopic tensile strength under both dry and wet conditions. |
Uncontrolled Keywords: | Cellulose, Paper, Wet strength, Spatial distribution, Swelling, Photo-crosslinking |
Status: | Publisher's Version |
URN: | urn:nbn:de:tuda-tuprints-235232 |
Classification DDC: | 500 Science and mathematics > 540 Chemistry |
Divisions: | 07 Department of Chemistry > Ernst-Berl-Institut > Fachgebiet Makromolekulare Chemie > Macromolecular and paper chemistry |
Date Deposited: | 10 Dec 2024 13:11 |
Last Modified: | 13 Dec 2024 10:53 |
SWORD Depositor: | Deep Green |
URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/23523 |
PPN: | 524554161 |
Export: |
View Item |