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ESR and ENDOR study on the radical ions of two non—alternant hydrocarbons: 1,3,5,7-tetra-tert-butyl-s-indacene and 2,7-di-tert-butyldicyclopenta [a,e] cyclooctene

Bachmann, Rainer ; Gerson, Fabian ; Gescheidt, Georg ; Hafner, Klaus (2022):
ESR and ENDOR study on the radical ions of two non—alternant hydrocarbons: 1,3,5,7-tetra-tert-butyl-s-indacene and 2,7-di-tert-butyldicyclopenta [a,e] cyclooctene. (Publisher's Version)
In: Magnetic resonance in chemistry, 33 (13), pp. 60-65. Wiley, e-ISSN 1097-458X,
DOI: 10.26083/tuprints-00022434,
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Status: Publisher's Version
Title: ESR and ENDOR study on the radical ions of two non—alternant hydrocarbons: 1,3,5,7-tetra-tert-butyl-s-indacene and 2,7-di-tert-butyldicyclopenta [a,e] cyclooctene
Language: English
Abstract:

The radical anions and radical cations of two alkyl-substituted non-alternant hydrocarbons, 1,3,5,7-tetra-tert-butyl-s-indacene and 2,7-di-tert-butyldicyclopenta [a,e] cyclooctene, were characterized by their proton coupling constants with the use of ESR and, in part, ENDOR spectroscopy. Considering the unusual electronic structures of the π-systems in question, these values agree fairly well with those predicted by simple MO theory. Also reported are the proton hyperfine data for the radical ions of the likewise alkyl-substituted non-alternant 8,16-diisopropyl-s-indaceno [1,2,3-cd:5,6,7-c′ d′] diphenalene.

Journal or Publication Title: Magnetic resonance in chemistry
Volume of the journal: 33
Issue Number: 13
Place of Publication: Darmstadt
Publisher: Wiley
Collation: 6 Seiten
Uncontrolled Keywords: ESR; ENDOR; radical anions; radical cations; s-indacene; dicyclopenta[a,e]cyclooctene; s-indaceno[l,2,3-cd:5,6,7-c’d’]diphenalene
Classification DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
Divisions: 07 Department of Chemistry > Organ Chemistry
Date Deposited: 21 Nov 2022 15:15
Last Modified: 21 Nov 2022 15:16
DOI: 10.26083/tuprints-00022434
Corresponding Links:
URN: urn:nbn:de:tuda-tuprints-224342
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/22434
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