Bachmann, Rainer ; Gerson, Fabian ; Gescheidt, Georg ; Hafner, Klaus (2022):
ESR and ENDOR study on the radical ions of two non—alternant hydrocarbons: 1,3,5,7-tetra-tert-butyl-s-indacene and 2,7-di-tert-butyldicyclopenta [a,e] cyclooctene. (Publisher's Version)
In: Magnetic resonance in chemistry, 33 (13), pp. 60-65. Wiley, e-ISSN 1097-458X,
DOI: 10.26083/tuprints-00022434,
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Magnetic Reson in Chemistry - December 1995 - Bachmann - ESR and ENDOR study on the radical ions of two non alternant.pdf Copyright Information: In Copyright. Download (1MB) |
Item Type: | Article |
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Origin: | Secondary publication service |
Status: | Publisher's Version |
Title: | ESR and ENDOR study on the radical ions of two non—alternant hydrocarbons: 1,3,5,7-tetra-tert-butyl-s-indacene and 2,7-di-tert-butyldicyclopenta [a,e] cyclooctene |
Language: | English |
Abstract: | The radical anions and radical cations of two alkyl-substituted non-alternant hydrocarbons, 1,3,5,7-tetra-tert-butyl-s-indacene and 2,7-di-tert-butyldicyclopenta [a,e] cyclooctene, were characterized by their proton coupling constants with the use of ESR and, in part, ENDOR spectroscopy. Considering the unusual electronic structures of the π-systems in question, these values agree fairly well with those predicted by simple MO theory. Also reported are the proton hyperfine data for the radical ions of the likewise alkyl-substituted non-alternant 8,16-diisopropyl-s-indaceno [1,2,3-cd:5,6,7-c′ d′] diphenalene. |
Journal or Publication Title: | Magnetic resonance in chemistry |
Volume of the journal: | 33 |
Issue Number: | 13 |
Place of Publication: | Darmstadt |
Publisher: | Wiley |
Collation: | 6 Seiten |
Uncontrolled Keywords: | ESR; ENDOR; radical anions; radical cations; s-indacene; dicyclopenta[a,e]cyclooctene; s-indaceno[l,2,3-cd:5,6,7-c’d’]diphenalene |
Classification DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
Divisions: | 07 Department of Chemistry > Organ Chemistry |
Date Deposited: | 21 Nov 2022 15:15 |
Last Modified: | 26 Apr 2023 08:05 |
DOI: | 10.26083/tuprints-00022434 |
Corresponding Links: | |
URN: | urn:nbn:de:tuda-tuprints-224342 |
URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/22434 |
PPN: | 507237161 |
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