Eckert-Maksić, Mirjana ; Gleiter, Rolf ; Hafner, Klaus ; Kläs, Heinz-Gerd (2022):
The Electronic Structure of 2-Azapentalenes. Photoelectron Spectroscopic Investigations. (Publisher's Version)
In: Chemische Berichte, 121 (7), pp. 1219-1223. Wiley, e-ISSN 1099-0682,
DOI: 10.26083/tuprints-00022378,
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Chemische Berichte - Juli 1988 - Eckert‐Maksi - The Electronic Structure of 2‐Azapentalenes Photoelectron Spectroscopic.pdf Copyright Information: In Copyright. Download (1MB) |
Item Type: | Article | ||||
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Origin: | Secondary publication service | ||||
Status: | Publisher's Version | ||||
Title: | The Electronic Structure of 2-Azapentalenes. Photoelectron Spectroscopic Investigations | ||||
Language: | English | ||||
Abstract: | The He(I) photoelectron spectra of eight 2-azapentalenes, substituted in 1,3-position by electron releasing groups (dimethylamino, ethoxy, and tert-butyl) revealed that the first four ionization energies (6.4–9.3 eV) are due to ionziation from π MO's. This assignment is based on the comparison with the PE data of 1,3-bis(dimethylamino)pentalene (10) and the results of MNDO calculations. The comparison between experiment and calculations suggests that the first two bands are due to ionizations from π MO's mainly localized in the pentalene moiety. |
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Journal or Publication Title: | Chemische Berichte | ||||
Volume of the journal: | 121 | ||||
Issue Number: | 7 | ||||
Place of Publication: | Darmstadt | ||||
Publisher: | Wiley | ||||
Classification DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie | ||||
Divisions: | 07 Department of Chemistry > Organ Chemistry | ||||
Date Deposited: | 22 Nov 2022 10:32 | ||||
Last Modified: | 22 Nov 2022 10:32 | ||||
DOI: | 10.26083/tuprints-00022378 | ||||
Corresponding Links: | |||||
URN: | urn:nbn:de:tuda-tuprints-223781 | ||||
URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/22378 | ||||
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