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Synthesis and Properties of the First [4.4]Ferrocenophane-1,3,15,17-tetrayne

Fabian, Kai H. H. ; Lindner, Hans-Jörg ; Nimmerfroh, Norbert ; Hafner, Klaus (2022):
Synthesis and Properties of the First [4.4]Ferrocenophane-1,3,15,17-tetrayne. (Publisher's Version)
In: Angewandte Chemie International Edition, 40 (18), pp. 3402-3405. Wiley, ISSN 1433-7851,
DOI: 10.26083/tuprints-00022368,

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Angew Chem Int Ed - 2001 - Fabian - Synthesis and Properties of the First 4 4 Ferrocenophane‐1 3 15 17‐tetrayne.pdf
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Status: Publisher's Version
Title: Synthesis and Properties of the First [4.4]Ferrocenophane-1,3,15,17-tetrayne
Language: English

Building butadiyne bridges: The kinetically stabilized 1,1′-diethynylferrocene, readily prepared from the pentafulvenoid allene 1, can be transformed into the [4.4]ferrocenophane 2 by oxidative coupling. This compound exhibits a remarkably symmetrical structure in which the electrons are delocalized through the butadiyne bridges; in the crystalline state 2 exists in a helical-chiral conformation.

Journal or Publication Title: Angewandte Chemie International Edition
Volume of the journal: 40
Issue Number: 18
Place of Publication: Darmstadt
Publisher: Wiley
Classification DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
Divisions: 07 Department of Chemistry > Organ Chemistry
Date Deposited: 28 Nov 2022 09:05
Last Modified: 28 Nov 2022 09:05
DOI: 10.26083/tuprints-00022368
Corresponding Links:
URN: urn:nbn:de:tuda-tuprints-223685
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/22368
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