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2,4,6,8-Tetracyanoazulene: A New Building Block for “Organic Metals”

Schmitt, Stefan ; Baumgarten, Martin ; Simon, Joachim ; Hafner, Klaus (2023)
2,4,6,8-Tetracyanoazulene: A New Building Block for “Organic Metals”.
In: Angewandte Chemie International Edition, 1998, 37 (8)
doi: 10.26083/tuprints-00022367
Article, Secondary publication, Publisher's Version

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Item Type: Article
Type of entry: Secondary publication
Title: 2,4,6,8-Tetracyanoazulene: A New Building Block for “Organic Metals”
Language: English
Date: 2023
Place of Publication: Darmstadt
Year of primary publication: 1998
Publisher: Wiley
Journal or Publication Title: Angewandte Chemie International Edition
Volume of the journal: 37
Issue Number: 8
DOI: 10.26083/tuprints-00022367
Corresponding Links:
Origin: Secondary publication service

Simply mixing solutions of the title compound 1 and tetrathiafulvene (TTF) in acetonitrile provides the charge-transfer complex 2. Here, 1 functions as a novel electron acceptor and is present in the complex as a radical anion. An electrical conductivity of up to 3 S cm⁻¹ was determined for 2 with a two-point powder measurement.

Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-223676
Classification DDC: 500 Science and mathematics > 540 Chemistry
Divisions: 07 Department of Chemistry > Clemens-Schöpf-Institut > Organ Chemistry
Date Deposited: 21 Mar 2023 10:55
Last Modified: 18 Aug 2023 06:38
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/22367
PPN: 510689043
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