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Synthesis and Structure of the First [2₂]Metallocenophanes

Hafner, Klaus ; Mink, Carsten ; Lindner, Hans Jörg (2023)
Synthesis and Structure of the First [2₂]Metallocenophanes.
In: Angewandte Chemie International Edition, 1994, 33 (14)
doi: 10.26083/tuprints-00022365
Article, Secondary publication, Publisher's Version

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Item Type: Article
Type of entry: Secondary publication
Title: Synthesis and Structure of the First [2₂]Metallocenophanes
Language: English
Date: 2023
Place of Publication: Darmstadt
Year of primary publication: 1994
Publisher: Wiley
Journal or Publication Title: Angewandte Chemie International Edition
Volume of the journal: 33
Issue Number: 14
DOI: 10.26083/tuprints-00022365
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Origin: Secondary publication service

The dark red Fe and colorless ZrCl2 complexes 2 are easily accessible from the doubly bridged biscyclopentadienes 1. The substantial torsion of the two eclipsing decks of the conformationally rigid ligand framework of 2 exposes the metal center and points to the potential of such complexes as catalysts for the stereoselective polymerization of alkenes.

Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-223656
Classification DDC: 500 Science and mathematics > 540 Chemistry
Divisions: 07 Department of Chemistry > Clemens-Schöpf-Institut > Organ Chemistry
Date Deposited: 07 Feb 2023 10:30
Last Modified: 21 Apr 2023 11:37
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/22365
PPN: 507137477
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