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Synthesis and Structure of 2,7-Di-tert-butyldicyclopenta[a,e]cyclooctene

Hafner, Klaus ; Thiele, Georg F. ; Mink, Carsten (2023)
Synthesis and Structure of 2,7-Di-tert-butyldicyclopenta[a,e]cyclooctene.
In: Angewandte Chemie International Edition, 1988, 27 (9)
doi: 10.26083/tuprints-00022364
Article, Secondary publication, Publisher's Version

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Item Type: Article
Type of entry: Secondary publication
Title: Synthesis and Structure of 2,7-Di-tert-butyldicyclopenta[a,e]cyclooctene
Language: English
Date: 2023
Place of Publication: Darmstadt
Year of primary publication: 1988
Publisher: Wiley
Journal or Publication Title: Angewandte Chemie International Edition
Volume of the journal: 27
Issue Number: 9
DOI: 10.26083/tuprints-00022364
Corresponding Links:
Origin: Secondary publication service

A completely planar, delocalized 14π-electron system which does not contain cyclically conjugated substructures characterizes the title compound (2). A productive synthesis of the 1,2-bis(tert-butylcyclopentadienyl)ethane (1) enabled the construction of the novel non-benzenoid aromatic hydrocarbon (2). which also contains one of the few planar eight-membered rings.

Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-223644
Classification DDC: 500 Science and mathematics > 540 Chemistry
Divisions: 07 Department of Chemistry > Clemens-Schöpf-Institut > Organ Chemistry
Date Deposited: 20 Mar 2023 10:46
Last Modified: 18 Aug 2023 06:36
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/22364
PPN: 510686885
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