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Phanes Derived from 1, 5- and 1, 7-Dihydro-s-indacene

Bickert, Peter ; Boekelheide, Virgil ; Hafner, Klaus (2022)
Phanes Derived from 1, 5- and 1, 7-Dihydro-s-indacene.
In: Angewandte Chemie International Edition, 2022, 21 (4)
doi: 10.26083/tuprints-00022354
Article, Secondary publication, Publisher's Version

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Item Type: Article
Type of entry: Secondary publication
Title: Phanes Derived from 1, 5- and 1, 7-Dihydro-s-indacene
Language: English
Date: 2022
Place of Publication: Darmstadt
Year of primary publication: 2022
Publisher: Wiley
Journal or Publication Title: Angewandte Chemie International Edition
Volume of the journal: 21
Issue Number: 4
DOI: 10.26083/tuprints-00022354
Corresponding Links:
Origin: Secondary publication service

Frontier orbital analysis of two conjugated, cyclic polyenes held face-to-face in close proximity suggests that when both polyenes have 4nπ-electron systems the interaction will be stabilizing, whereas when both have (4n+2)π-electron systems the interaction will be destabilizing[¹]. To test this prediction experimentally it would be of especial interest to examine phanes having nonbenzenoid aromatic and also antiaromatic decks as model compounds.

Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-223543
Additional Information:

German version: 10.26083/tuprints-00022247

Classification DDC: 500 Science and mathematics > 540 Chemistry
Divisions: 07 Department of Chemistry > Clemens-Schöpf-Institut > Organ Chemistry
Date Deposited: 22 Nov 2022 10:01
Last Modified: 21 Apr 2023 11:19
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/22354
PPN: 507135911
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