Grätz, Sven ; Zink, Sebastian ; Kraffczyk, Hanna ; Rose, Marcus ; Borchardt, Lars (2021):
Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors. (Publisher's Version)
In: Beilstein Journal of Organic Chemistry, 15, pp. 1154-1161. Beilstein-Institut zur Förderung der Chemischen Wissenschaften, ISSN 1860-5397,
DOI: 10.26083/tuprints-00019905,
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Item Type: | Article |
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Origin: | Secondary publication service |
Status: | Publisher's Version |
Title: | Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors |
Language: | English |
Abstract: | This study elucidates a mechanochemical polymerization reaction towards a hyper-crosslinked polymer as an alternative to conventional solvent-based procedures. The swift and solvent-free Friedel–Crafts alkylation reaction yields a porous polymer with surface areas of up to 1720 m2g −1 and pore volumes of up to 1.55 cm3g −1. The application of LAG (liquid-assisted grinding) revealed a profound impact of the liquid´s boiling point on the textural properties of the obtained polymer materials. Finally, the materials are characterized by vapour sorption experiments with benzene and cyclohexane. |
Journal or Publication Title: | Beilstein Journal of Organic Chemistry |
Volume of the journal: | 15 |
Publisher: | Beilstein-Institut zur Förderung der Chemischen Wissenschaften |
Classification DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
Divisions: | 07 Department of Chemistry > Fachgebiet Technische Chemie > Technische Chemie II |
Date Deposited: | 18 Nov 2021 10:47 |
Last Modified: | 18 Nov 2021 10:47 |
DOI: | 10.26083/tuprints-00019905 |
Corresponding Links: | |
URN: | urn:nbn:de:tuda-tuprints-199053 |
URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/19905 |
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