Grätz, Sven ; Zink, Sebastian ; Kraffczyk, Hanna ; Rose, Marcus ; Borchardt, Lars (2021)
Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors.
In: Beilstein Journal of Organic Chemistry, 2021, 15
doi: 10.26083/tuprints-00019905
Article, Secondary publication, Publisher's Version
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| Item Type: | Article |
|---|---|
| Type of entry: | Secondary publication |
| Title: | Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors |
| Language: | English |
| Date: | 2021 |
| Place of Publication: | Darmstadt |
| Year of primary publication: | 2021 |
| Publisher: | Beilstein-Institut zur Förderung der Chemischen Wissenschaften |
| Journal or Publication Title: | Beilstein Journal of Organic Chemistry |
| Volume of the journal: | 15 |
| DOI: | 10.26083/tuprints-00019905 |
| Corresponding Links: | |
| Origin: | Secondary publication service |
| Abstract: | This study elucidates a mechanochemical polymerization reaction towards a hyper-crosslinked polymer as an alternative to conventional solvent-based procedures. The swift and solvent-free Friedel–Crafts alkylation reaction yields a porous polymer with surface areas of up to 1720 m2g −1 and pore volumes of up to 1.55 cm3g −1. The application of LAG (liquid-assisted grinding) revealed a profound impact of the liquid´s boiling point on the textural properties of the obtained polymer materials. Finally, the materials are characterized by vapour sorption experiments with benzene and cyclohexane. |
| Status: | Publisher's Version |
| URN: | urn:nbn:de:tuda-tuprints-199053 |
| Classification DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Divisions: | 07 Department of Chemistry > Fachgebiet Technische Chemie > Technische Chemie II |
| Date Deposited: | 18 Nov 2021 10:47 |
| Last Modified: | 16 Aug 2023 05:54 |
| URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/19905 |
| PPN: | 510632793 |
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