Abstract: |
The mode coupling theory (MCT) for the ideal liquid glass transition, which was worked out for simple liquids mainly by Gotze, Sjogren, and their co-workers, is extended to a molecular liquid of linear and rigid molecules. By use of the projection formalism of Zwanzig and Mori an equation of motion is derived for the correlators S[sub lm,l[sup (prime)]m[sup (prime)]]([bold q],t) of the tensorial one-particle density rho [sub lm]([bold q],t), which contains the orientational degrees of freedom for l(greater-than)0. Application of the mode coupling approximation to the memory kernel results into a closed set of equations for S[sub lm,l[sup (prime)]m[sup (prime)]]([bold q],t), which requires the static correlators S[sub lm,l[sup (prime)]m[sup (prime)]]([bold q]) as the only input quantities. The corresponding MCT equations for the nonergodicity parameters f[sub l][sup m](q)(equivalent)f[sub lm,lm](q[bold e][sub 3]) are solved for a system of dipolar hard spheres by restricting the values for l to 0 and 1. Depending on the packing fraction cursive-phi and on the temperature T, three different phases exist: a liquid phase, where translational (TDOF's) (l=0) and orientational (ODOF's) (l=1) degrees of freedom are ergodic, a phase where the TDOF are frozen into a (nonergodic) glassy state, whereas the ODOF's remain ergodic, and finally a glassy phase where both, TDOF's and ODOF's, are nonergodic. From the nonergodicity parameters f[sub 0][sup 0](q) and f[sub 1][sup 1](q) for q=0, we may conclude that the corresponding relaxation strength of the alpha peak of the compressibility can be much smaller than the corresponding strength of the dielectric function. |
Uncontrolled Keywords: |
cond-mat, Soft Condensed Matter, mode coupling theory, Gotze, Sjogren,projection formalism of Zwanzig and Mori, mode coupling approximation, nonergodicity parameter, translational, orientational degrees of freedom, memory kernel, dipolar hard spheres, packing fraction, static correlators |
Alternative keywords: |
Alternative keywords | Language |
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cond-mat, Soft Condensed Matter, mode coupling theory, Gotze, Sjogren,projection formalism of Zwanzig and Mori, mode coupling approximation, nonergodicity parameter, translational, orientational degrees of freedom, memory kernel, dipolar hard spheres, packing fraction, static correlators | English |
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