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POSS-Containing Polymethacrylates on Cellulose-Based Substrates: Immobilization and Ceramic Formation

Rüttiger, Christian ; Vowinkel, Steffen ; Herzog, Nicole ; Hofmann, Kathrin ; Ionescu, Emanuel ; Gallei, Markus (2019)
POSS-Containing Polymethacrylates on Cellulose-Based Substrates: Immobilization and Ceramic Formation.
In: Coatings, 2018, 8 (12)
Article, Secondary publication, Publisher's Version

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Item Type: Article
Type of entry: Secondary publication
Title: POSS-Containing Polymethacrylates on Cellulose-Based Substrates: Immobilization and Ceramic Formation
Language: English
Date: 21 February 2019
Place of Publication: Darmstadt
Year of primary publication: 2018
Publisher: MDPI
Journal or Publication Title: Coatings
Volume of the journal: 8
Issue Number: 12
Corresponding Links:
Origin: Secondary publication via sponsored Golden Open Access
Abstract:

The combination of cellulose-based materials and functional polymers is a promising approach for the preparation of porous, biotemplated ceramic materials. Within this study, cellulose substrates were functionalized with a surface-attached initiator followed by polymerization of (3-methacryloxypropyl)heptaisobutyl-T8-silsesquioxane (MAPOSS) by means of surface-initiated atom transfer radical polymerization (ATRP). Successful functionalization was proven by infrared (IR) spectroscopy as well as by contact angle (CA) measurements. Thermal analysis of the polymer-modified cellulose substrates in different atmospheres (nitrogen and air) up to 600 ◦C led to porous carbon materials featuring the pristine fibre-like structure of the cellulose material as shown by scanning electron microscopy (SEM). Interestingly, spherical, silicon-containing domains were present at the surface of the cellulose-templated carbon fibres after further ceramisation at 1600 ◦C, as investigated by energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD) measurements.

Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-85037
Classification DDC: 500 Science and mathematics > 540 Chemistry
Divisions: 07 Department of Chemistry
Date Deposited: 21 Feb 2019 12:15
Last Modified: 20 Oct 2023 09:10
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/8503
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