Bonn, Mischa ; Hess, Christian ; Funk, Stephan ; Miners, James H. ; Persson, Bo N. J. ; Wolf, Martin ; Ertl, Gerhard (2024)
Femtosecond Surface Vibrational Spectroscopy of CO Adsorbed on Ru(001) during Desorption.
In: Physical Review Letters, 2000, 84 (20)
doi: 10.26083/tuprints-00026903
Article, Secondary publication, Publisher's Version
![[img]](https://tuprints.ulb.tu-darmstadt.de/style/images/fileicons/text.png) |
Text
PhysRevLett.84.4653.pdf Copyright Information: In Copyright. Download (222kB) |
| Item Type: | Article |
|---|---|
| Type of entry: | Secondary publication |
| Title: | Femtosecond Surface Vibrational Spectroscopy of CO Adsorbed on Ru(001) during Desorption |
| Language: | English |
| Date: | 23 April 2024 |
| Place of Publication: | Darmstadt |
| Year of primary publication: | 2000 |
| Place of primary publication: | College Park, MD |
| Publisher: | American Physical Society |
| Journal or Publication Title: | Physical Review Letters |
| Volume of the journal: | 84 |
| Issue Number: | 20 |
| DOI: | 10.26083/tuprints-00026903 |
| Corresponding Links: | |
| Origin: | Secondary publication service |
| Abstract: | Using time-resolved sum-frequency generation spectroscopy, the C—O stretch vibration of carbon monoxide adsorbed on a single-crystal Ru(001) surface is investigated during femtosecond near-IR laser excitation leading to desorption. A large transient redshift, a broadening of the resonance, and a strong decrease in intensity are observed. These originate from coupling of the C—O stretch to low-frequency modes, especially the frustrated rotation, that are highly excited in the desorption process. |
| Status: | Publisher's Version |
| URN: | urn:nbn:de:tuda-tuprints-269032 |
| Classification DDC: | 500 Science and mathematics > 530 Physics 500 Science and mathematics > 540 Chemistry |
| Date Deposited: | 23 Apr 2024 08:20 |
| Last Modified: | 23 Apr 2024 08:20 |
| URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/26903 |
| PPN: | |
| Export: |
 |
View Item |
Drucken
Impressum