Niemeier, Johannes ; Engel, Rebecca V. ; Rose, Marcus (2023)
Is water a suitable solvent for the catalytic amination of alcohols?
In: Green Chemistry, 2017, 19 (12)
doi: 10.26083/tuprints-00024540
Article, Secondary publication, Publisher's Version
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Item Type: | Article |
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Type of entry: | Secondary publication |
Title: | Is water a suitable solvent for the catalytic amination of alcohols? |
Language: | English |
Date: | 11 December 2023 |
Place of Publication: | Darmstadt |
Year of primary publication: | 27 March 2017 |
Place of primary publication: | Cambridge |
Publisher: | Royal Society of Chemistry |
Journal or Publication Title: | Green Chemistry |
Volume of the journal: | 19 |
Issue Number: | 12 |
DOI: | 10.26083/tuprints-00024540 |
Corresponding Links: | |
Origin: | Secondary publication service |
Abstract: | The catalytic conversion of biomass and biogenic platform chemicals typically requires the use of solvents. Water is present already in the raw materials and in most cases a suitable solvent for the typically highly polar substrates. Hence, the development of novel catalytic routes for further processing would profit from the optimization of the reaction conditions in the aqueous phase mainly for energetic reasons by avoiding the initial water separation. Herein, we report the amination of biogenic alcohols in aqueous solutions using solid Ru-based catalysts and ammonia as a reactant. The influence of different support materials and bimetallic catalysts is investigated for the amination of isomannide as a biogenic diol. Most importantly, the transferability of the reaction conditions to various other primary and secondary alcohols is successfully proved. Hence, water appears to be a suitable solvent for the sustainable production of biogenic amines and offers great potential for further process development. |
Status: | Publisher's Version |
URN: | urn:nbn:de:tuda-tuprints-245405 |
Classification DDC: | 500 Science and mathematics > 540 Chemistry |
Divisions: | 07 Department of Chemistry > Ernst-Berl-Institut > Fachgebiet Technische Chemie |
Date Deposited: | 11 Dec 2023 10:41 |
Last Modified: | 15 Dec 2023 10:46 |
URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/24540 |
PPN: | 513970185 |
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