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Liquid phase aromatization of bio-based ketones over a stable solid acid catalyst under batch and continuous flow conditions

Reif, Phillip ; Gupta, Navneet Kumar ; Rose, Marcus (2023)
Liquid phase aromatization of bio-based ketones over a stable solid acid catalyst under batch and continuous flow conditions.
In: Catalysis Communications, 2022, 163
doi: 10.26083/tuprints-00024523
Article, Secondary publication, Publisher's Version

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Item Type: Article
Type of entry: Secondary publication
Title: Liquid phase aromatization of bio-based ketones over a stable solid acid catalyst under batch and continuous flow conditions
Language: English
Date: 20 November 2023
Place of Publication: Darmstadt
Year of primary publication: March 2022
Place of primary publication: Amsterdam
Publisher: Elsevier
Journal or Publication Title: Catalysis Communications
Volume of the journal: 163
Collation: 7 Seiten
DOI: 10.26083/tuprints-00024523
Corresponding Links:
Origin: Secondary publication service
Abstract:

Herein, we describe a one-step process for renewable aromatics from biomass-derived ketones over solid acid catalysts under liquid phase batch and flow conditions. The ion exchange resin was highly active for aromatics due to high acidic strength but leaching of acidic sites caused low stability. In contrary, zeolite HY showed a lower activity but higher stability in batch by regenerability and was stable in flow for 250 min-on-stream. HY is further applicable for the conversion of higher ketones (butanone and pentanone). This work contributes towards an industrially important aromatic production from biogenic ketones and thus an economical and sustainable process.

Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-245235
Classification DDC: 500 Science and mathematics > 540 Chemistry
Divisions: 07 Department of Chemistry > Ernst-Berl-Institut > Fachgebiet Technische Chemie
Date Deposited: 20 Nov 2023 10:59
Last Modified: 27 Nov 2023 07:21
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/24523
PPN: 51347112X
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