Kaps, Alexander ; Plenio, Herbert (2023)
Facile Synthesis of Triptycene‐Azolium Salts and NHC‐Metal Complexes.
In: European Journal of Inorganic Chemistry, 2023, 26 (18)
doi: 10.26083/tuprints-00024323
Article, Secondary publication, Publisher's Version
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| Item Type: | Article |
|---|---|
| Type of entry: | Secondary publication |
| Title: | Facile Synthesis of Triptycene‐Azolium Salts and NHC‐Metal Complexes |
| Language: | English |
| Date: | 18 July 2023 |
| Place of Publication: | Darmstadt |
| Year of primary publication: | 2023 |
| Publisher: | Wiley-VCH |
| Journal or Publication Title: | European Journal of Inorganic Chemistry |
| Volume of the journal: | 26 |
| Issue Number: | 18 |
| Collation: | 11 Seiten |
| DOI: | 10.26083/tuprints-00024323 |
| Corresponding Links: | |
| Origin: | Secondary publication DeepGreen |
| Abstract: | The cycloaddition reactions of eleven substituted anthracenes with nosylated quinone imines provides a convenient route to the respective triptycenes. Following re‐aromatization, selective O‐butylation and cleavage of the nosyl‐group the respective triptycene anilines are obtained, which are converted into the respective imidazolium salts according to established procedures. Deprotonation of the imidazolium salts provide new triptycene‐NHC‐metal complexes (M=AuCl, RhCl(cod), IrCl(cod), RhCl(CO)₂, IrCl(CO)₂, PdI₂(py), PtCl₂(py), Pd(allyl)Cl) with unusual ligand sterics. |
| Uncontrolled Keywords: | anthracene, cycloaddition, NHC ligands, transition metals, triptycene |
| Identification Number: | e202300178 |
| Status: | Publisher's Version |
| URN: | urn:nbn:de:tuda-tuprints-243239 |
| Additional Information: | This article also appears in: NHC Ligands in Organometallic Chemistry and Catalysis |
| Classification DDC: | 500 Science and mathematics > 540 Chemistry |
| Divisions: | 07 Department of Chemistry > Eduard Zintl-Institut > Fachgebiet Anorganische Chemie > Organometallchemie |
| Date Deposited: | 18 Jul 2023 12:36 |
| Last Modified: | 17 Oct 2023 07:32 |
| SWORD Depositor: | Deep Green |
| URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/24323 |
| PPN: | 512236534 |
| Export: |
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