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Temperature‐dependent mechanical and oxidation behavior of in situ formed ZrN/ZrO₂‐containing Si₃N₄‐based composite

Liu, Jiongjie ; Li, Wei ; Ricohermoso, Emmanuel III ; Qiao, Zhuihui ; Dai, Qingwen ; Liu, Xingmin ; Xie, Wenjie ; Ionescu, Emanuel ; Weidenkaff, Anke ; Riedel, Ralf (2023)
Temperature‐dependent mechanical and oxidation behavior of in situ formed ZrN/ZrO₂‐containing Si₃N₄‐based composite.
In: Journal of the American Ceramic Society, 2023, 106 (8)
doi: 10.26083/tuprints-00024300
Article, Secondary publication, Publisher's Version

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Item Type: Article
Type of entry: Secondary publication
Title: Temperature‐dependent mechanical and oxidation behavior of in situ formed ZrN/ZrO₂‐containing Si₃N₄‐based composite
Language: English
Date: 24 November 2023
Place of Publication: Darmstadt
Year of primary publication: 2023
Place of primary publication: Oxford
Publisher: Wiley-Blackwell
Journal or Publication Title: Journal of the American Ceramic Society
Volume of the journal: 106
Issue Number: 8
DOI: 10.26083/tuprints-00024300
Corresponding Links:
Origin: Secondary publication DeepGreen
Abstract:

In this work, Si₃N₄ and Zr(NO₃)₄ were used as raw materials to prepare ZrN/ZrO₂‐containing Si₃N₄‐based ceramic composite. The processing, phase composition, and microstructure of the composite were investigated. Hardness and fracture toughness of the ceramics were evaluated via Vickers indentation in Ar at 25°C, 300°C, 600°C, and 900°C. During spark plasma sintering, Zr(NO₃)₄ was transformed into tetragonal ZrO₂, which further reacted with Si₃N₄, resulting in the formation of ZrN. The introduction of ZrN enhanced the high‐temperature mechanical properties of the composite, and its hardness and fracture toughness reached 13.4 GPa and 6.1 MPa·m¹/² at 900°C, respectively. The oxidation experiment was carried out in air at 1000°C, 1300°C, and 1500°C for 5 h. It was shown that high‐temperature oxidation promoted the formation and growth of porous oxide layers. The microstructure and phase composition of the formed oxide layers were investigated in detail. Finally, it was identified that the obtained composite exhibited a higher thermal diffusivity than that of monolithic Si₃N₄ in the temperature range of 100°C–1000°C.

Uncontrolled Keywords: mechanical properties, oxidation, silicon nitride, thermal properties, zirconia
Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-243003
Classification DDC: 500 Science and mathematics > 540 Chemistry
Divisions: 11 Department of Materials and Earth Sciences > Material Science > Dispersive Solids
11 Department of Materials and Earth Sciences > Material Science > Materials and Resources
Date Deposited: 24 Nov 2023 13:45
Last Modified: 29 Nov 2023 07:26
SWORD Depositor: Deep Green
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/24300
PPN: 513493891
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