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A Long‐Overlooked Pitfall in Rechargeable Zinc-Air Batteries: Proper Electrode Balancing

Deckenbach, Daniel ; Schneider, Jörg J. (2023)
A Long‐Overlooked Pitfall in Rechargeable Zinc-Air Batteries: Proper Electrode Balancing.
In: Advanced Materials Interfaces, 2023, 10 (15)
doi: 10.26083/tuprints-00024291
Article, Secondary publication, Publisher's Version

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Item Type: Article
Type of entry: Secondary publication
Title: A Long‐Overlooked Pitfall in Rechargeable Zinc-Air Batteries: Proper Electrode Balancing
Language: English
Date: 7 August 2023
Place of Publication: Darmstadt
Year of primary publication: 2023
Publisher: Wiley-VCH
Journal or Publication Title: Advanced Materials Interfaces
Volume of the journal: 10
Issue Number: 15
Collation: 16 Seiten
DOI: 10.26083/tuprints-00024291
Corresponding Links:
Origin: Secondary publication DeepGreen
Abstract:

In times of an ever‐increasing demand for portable energy storage systems, post‐lithium‐based battery systems are increasingly coming into the focus of current research. In this realm, zinc–air batteries can be considered a very promising candidate to expand the existing portfolio of lithium‐based rechargeable battery systems due to their high theoretical energy density of 1086 Wh kg⁻¹. Despite a steady increase in research over the past 5 years, a breakthrough in realizing fully electrically rechargeable zinc–air batteries has yet to come. This perspective article highlights pitfalls that have probably hampered the development of rechargeable zinc–air batteries over years. This involves a fundamental evaluation of the zinc–air battery system, whereby fallacies of an alleged rechargeability are uncovered. Especially, the electrode balancing of the zinc anode as well as the interface between anode and electrolyte is focused herein. Known phenomena such as morphological changes are re‐evaluated by taking the contrasting battery stresses from shallow discharge to a highly desirable deep discharge into account. Existing challenges are discussed and prospected based on current approaches aiming to shed new light on a fundamental understanding and an opening of new avenues for rechargeability in zinc–air batteries.

Uncontrolled Keywords: metal anode, rechargeability, zinc, zinc oxide, zinc–air battery
Identification Number: 2202494
Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-242912
Classification DDC: 600 Technology, medicine, applied sciences > 660 Chemical engineering
Divisions: 07 Department of Chemistry > Eduard Zintl-Institut > Fachgebiet Anorganische Chemie
Date Deposited: 07 Aug 2023 08:24
Last Modified: 11 Oct 2023 07:58
SWORD Depositor: Deep Green
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/24291
PPN: 512208328
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