Hafner, Klaus ; Goliasch, Karl (2023)
Zur Kenntnis des Cyclopentadienons.
In: Angewandte Chemie, 1960, 72 (21)
doi: 10.26083/tuprints-00022054
Article, Secondary publication, Publisher's Version
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Angewandte Chemie - 7 November 1960 - Hafner - Zur Kenntnis des Cyclopentadienons.pdf Copyright Information: In Copyright. Download (1MB) |
| Item Type: | Article |
|---|---|
| Type of entry: | Secondary publication |
| Title: | Zur Kenntnis des Cyclopentadienons |
| Language: | German |
| Date: | 23 January 2023 |
| Place of Publication: | Darmstadt |
| Year of primary publication: | 1960 |
| Publisher: | Wiley |
| Journal or Publication Title: | Angewandte Chemie |
| Volume of the journal: | 72 |
| Issue Number: | 21 |
| DOI: | 10.26083/tuprints-00022054 |
| Corresponding Links: | |
| Origin: | Secondary publication service |
| Abstract: | Cyclopenten-(2)-on-(1) gibt mit N-Bromsuccinimid 5-Brom-cyclopenten-(2)-on-(1) (I) (84 %, Kp₀,₈ 50-51 °C). Dieses spaltet in Ather in Gegenwart von Basen (besonders gut mit Dilthylamin) HBr ab unter Bildung von Cyclopentadienon (II), das sich sofort zum 1.8-Diketo-4.7-methano-3a.4.7.7a-tetrahydroinden (III) (76 %, Fp 103-104 °C, Kp₁₁ 146-148 °C) dimerisiert. |
| Status: | Publisher's Version |
| URN: | urn:nbn:de:tuda-tuprints-220542 |
| Classification DDC: | 500 Science and mathematics > 540 Chemistry |
| Divisions: | 07 Department of Chemistry > Clemens-Schöpf-Institut > Organ Chemistry |
| Date Deposited: | 23 Jan 2023 10:55 |
| Last Modified: | 19 Sep 2023 18:02 |
| URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/22054 |
| PPN: | 506815390 |
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