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The Effect of Co-Monomer Content on the Swelling/Shrinking and Mechanical Behaviour of Individually Adsorbed PNIPAM Microgel Particles

Burmistrova, Anna ; Richter, Marcel ; Eisele, Michael ; Üzüm, Cagri ; Klitzing, Regine von (2021)
The Effect of Co-Monomer Content on the Swelling/Shrinking and Mechanical Behaviour of Individually Adsorbed PNIPAM Microgel Particles.
In: Polymers, 2011, 3 (4)
doi: 10.26083/tuprints-00019053
Article, Secondary publication, Publisher's Version

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Item Type: Article
Type of entry: Secondary publication
Title: The Effect of Co-Monomer Content on the Swelling/Shrinking and Mechanical Behaviour of Individually Adsorbed PNIPAM Microgel Particles
Language: English
Date: 2021
Place of Publication: Darmstadt
Year of primary publication: 2011
Publisher: MDPI
Journal or Publication Title: Polymers
Volume of the journal: 3
Issue Number: 4
DOI: 10.26083/tuprints-00019053
Corresponding Links:
Origin: Secondary publication service
Abstract:

The swelling/deswelling behaviour of microgel particles in the bulk and at the surface was studied and correlated to their mechanical properties. We focused on two kinds of particles: pure PNIPAM and PNIPAM-co-AAc particles. It was shown that the two step volume phase transition found for PNIPAM-co-AAc particles in the bulk disappears after the adsorption at the surface and only a one step transition was identified. The transition temperature increased strongly with increasing the co-monomer content. The dependence of the Young’s modulus of the adsorbed microgel particles on the temperature and the co-monomer content was discussed. The investigations were performed via DLS and SFM.

Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-190530
Classification DDC: 500 Science and mathematics > 530 Physics
Divisions: 05 Department of Physics > Institute for Condensed Matter Physics
Date Deposited: 03 Sep 2021 12:55
Last Modified: 08 Aug 2023 09:07
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/19053
PPN: 510415237
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