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Combining Soft Polysilazanes with Melt-Shear Organization of Core−Shell Particles: On the Road to Polymer-Templated Porous Ceramics

Boehm, Anna K. ; Ionescu, Emanuel ; Koch, Marcus ; Gallei, Markus (2023)
Combining Soft Polysilazanes with Melt-Shear Organization of Core−Shell Particles: On the Road to Polymer-Templated Porous Ceramics.
In: Molecules, 2019, 24 (19)
doi: 10.26083/tuprints-00016225
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Item Type: Article
Type of entry: Secondary publication
Title: Combining Soft Polysilazanes with Melt-Shear Organization of Core−Shell Particles: On the Road to Polymer-Templated Porous Ceramics
Language: English
Date: 21 November 2023
Place of Publication: Darmstadt
Year of primary publication: 2019
Place of primary publication: Basel
Publisher: MDPI
Journal or Publication Title: Molecules
Volume of the journal: 24
Issue Number: 19
Collation: 16 Seiten
DOI: 10.26083/tuprints-00016225
Corresponding Links:
Origin: Secondary publication DeepGreen
Abstract:

The preparation of ordered macroporous SiCN ceramics has attracted significant interest and is an attractive area for various applications, e.g., in the fields of catalysis, gas adsorption, or membranes. Non-oxidic ceramics, such as SiCN, own a great stability based on the covalent bonds between the containing elements, which leads to interesting properties concerning resistance and stability at high temperature. Their peculiar properties have become more and more important for a manifold of applications, like catalysis or separation processes, at high temperatures. Within this work, a feasible approach for the preparation of ordered porous materials by taking advantage of polymer-derived ceramics is presented. To gain access to free-standing films consisting of porous ceramic materials, the combination of monodisperse organic polymer-based colloids with diameters of 130 nm and 180 nm featuring a processable preceramic polymer is essential. For this purpose, the tailored design of hybrid organic/inorganic particles featuring anchoring sites for a preceramic polymer in the soft shell material is developed. Moreover, polymer-based core particles are used as sacrificial template for the generation of pores, while the preceramic shell polymer can be converted to the ceramic matrix after thermal treatment. Two different routes for the polymer particles, which can be obtained by emulsion polymerization, are followed for covalently linking the preceramic polysilazane Durazane1800 (Merck, Germany): (i) Free radical polymerization and (ii) atom transfer radical polymerization (ATRP) conditions. These hybrid hard core/soft shell particles can be processed via the so-called melt-shear organization for the one-step preparation of free-standing particle films. A major advantage of this technique is the absence of any solvent or dispersion medium, enabling the core particles to merge into ordered particle stacks based on the soft preceramic shell. Subsequent ceramization of the colloidal crystal films leads to core particle degradation and transformation into porous ceramics with ceramic yields of 18–54%.

Uncontrolled Keywords: polymer particle synthesis, particle processing, polymer chemistry, preceramic materials, melt-shear organization, polymer derived ceramic, core–shell
Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-162257
Additional Information:

This article belongs to the Special Issue Advances in Porous Materials

Classification DDC: 500 Science and mathematics > 540 Chemistry
Divisions: 11 Department of Materials and Earth Sciences > Material Science > Dispersive Solids
Date Deposited: 21 Nov 2023 13:55
Last Modified: 23 Nov 2023 13:12
SWORD Depositor: Deep Green
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/16225
PPN: 51339561X
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