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Investigations into Supramolecular Lyotropic Liquid Crystals Based on 1,3,5‐Benzenetricarboxaramides by NMR Spectroscopy

Knoll, Kevin ; Kostner, Tobias ; Lorenz, Christian ; Thiele, Christina M. (2022)
Investigations into Supramolecular Lyotropic Liquid Crystals Based on 1,3,5‐Benzenetricarboxaramides by NMR Spectroscopy.
In: European Journal of Organic Chemistry, 2022, 2022 (11)
doi: 10.26083/tuprints-00021544
Article, Secondary publication, Publisher's Version

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Item Type: Article
Type of entry: Secondary publication
Title: Investigations into Supramolecular Lyotropic Liquid Crystals Based on 1,3,5‐Benzenetricarboxaramides by NMR Spectroscopy
Language: English
Date: 24 June 2022
Place of Publication: Darmstadt
Year of primary publication: 2022
Publisher: Wiley-VCH
Journal or Publication Title: European Journal of Organic Chemistry
Volume of the journal: 2022
Issue Number: 11
Collation: 5 Seiten
DOI: 10.26083/tuprints-00021544
Corresponding Links:
Origin: Secondary publication DeepGreen
Abstract:

New supramolecular lyotropic liquid crystals (LLC) based on 1,3,5‐benzenetricarboxamides (BTAs) with n‐alkylaniline sidechains are described. Using NMR spectroscopy, we investigate the effects of different chain lengths along the homologous series and of non‐BTA additives on liquid crystalline behaviour. From this, we attempt to answer two questions: First, how aliphatic chain length and the addition of further aromatic rings affect the self‐assembly process in general and compared to previously reported systems with purely aliphatic sidechains. Second, whether these modifications are suitable to increases the resulting LLC phases’ resilience against disrupting effects of further, non‐BTA additives.

Uncontrolled Keywords: 2H-NMR, BTAs, Lyotropic liquid crystals, Self-assembly, Supramolecular chemistry
Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-215443
Classification DDC: 500 Science and mathematics > 540 Chemistry
Divisions: 07 Department of Chemistry > Clemens-Schöpf-Institut > Organ Chemistry
Date Deposited: 24 Jun 2022 13:00
Last Modified: 14 Nov 2023 19:04
SWORD Depositor: Deep Green
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/21544
PPN: 499644468
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