Brodrecht, Martin ; Kumari, Bharti ; Breitzke, Hergen ; Gutmann, Torsten ; Buntkowsky, Gerd (2021):
Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions. (Publisher's Version)
In: Zeitschrift für Physikalische Chemie, 232 (7-8), pp. 1127-1146. De Gruyter, ISSN 0942-9352, e-ISSN 2196-7156,
DOI: 10.26083/tuprints-00019694,
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Item Type: | Article |
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Origin: | Secondary publication service |
Status: | Publisher's Version |
Title: | Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions |
Language: | English |
Abstract: | A series of novel functionalized mesoporous silica-based materials with well-defined pore diameters, surface functionalization and surface morphology is synthesized by co-condensation or grafting techniques and characterized by solid-state NMR spectroscopy, DNP enhanced solid state-NMR and thermodynamic techniques. These materials are employed as host-systems for small-guest molecules like water, small alcohols, carbonic acids, small aromatic molecules, binary mixtures and others. The phase-behavior of these confined guests is studied by combinations of one dimensional solid-state NMR techniques (¹HMAS, ²H-line shape analysis, ¹³C CPMAS) and two-dimensional correlation experiments like ¹H-²⁹Si- solid-state HETCOR. |
Journal or Publication Title: | Zeitschrift für Physikalische Chemie |
Volume of the journal: | 232 |
Issue Number: | 7-8 |
Publisher: | De Gruyter |
Classification DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
Divisions: | 07 Department of Chemistry > Physical Chemistry |
Date Deposited: | 01 Oct 2021 11:35 |
Last Modified: | 01 Oct 2021 11:36 |
DOI: | 10.26083/tuprints-00019694 |
Corresponding Links: | |
URN: | urn:nbn:de:tuda-tuprints-196940 |
Additional Information: | Keywords: confinement; micro-phase separation; solid-state-NMR |
URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/19694 |
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