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Synthesis and Characterization of High‐Entropy CrMoNbTaVW Thin Films Using High‐Throughput Methods

Schweidler, Simon ; Schopmans, Henrik ; Reiser, Patrick ; Boltynjuk, Evgeniy ; Olaya, Jhon Jairo ; Singaraju, Surya Abhishek ; Fischer, Franz ; Hahn, Horst ; Friederich, Pascal ; Velasco, Leonardo (2023)
Synthesis and Characterization of High‐Entropy CrMoNbTaVW Thin Films Using High‐Throughput Methods.
In: Advanced Engineering Materials, 2022, 25 (2)
doi: 10.26083/tuprints-00023731
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Item Type: Article
Type of entry: Secondary publication
Title: Synthesis and Characterization of High‐Entropy CrMoNbTaVW Thin Films Using High‐Throughput Methods
Language: English
Date: 28 April 2023
Place of Publication: Darmstadt
Year of primary publication: 2022
Publisher: Wiley-VCH
Journal or Publication Title: Advanced Engineering Materials
Volume of the journal: 25
Issue Number: 2
Collation: 7 Seiten
DOI: 10.26083/tuprints-00023731
Corresponding Links:
Origin: Secondary publication DeepGreen
Abstract:

High‐entropy alloys (HEAs) or complex concentrated alloys (CCAs) offer a huge research area for new material compositions and potential applications. Since the combination of several elements sometimes leads to unexpected and unpredictable material properties. In addition to the element combinations, the optimization of the element proportions in CCAs and HEAs is also a decisive factor in tailoring desired material properties. However, it is almost impossible to achieve the composition and characterization of CCAs and HEAs with a sufficient number of compositions by conventional experiments. Therefore, an optimized high‐throughput magnetron sputtering synthesis to fabricate a new HEA gradient layer of six elements is presented. With this approach, the compositional space of the HEA system CrMoNbTaVW can be studied in different subsections to determine the influence of the individual elements and their combinations on the structure, morphology, and physical properties (hardness and resistivity). It is found that the Cr‐, Ta‐, and W‐rich phases, which have a grain size of 10–11 nm, exhibit the hardest mechanical properties, whereas V‐, Ta‐, and Cr‐rich compounds exhibit the highest electrical resistivity. The combination of high‐throughput synthesis, automated analysis tools, and automated data interpretation enables rapid and time‐efficient characterization of the novel CrMoNbTaVW gradient film.

Uncontrolled Keywords: DC sputtering, hardness, high-entropy materials, high-throughput, materials libraries, phase diagram, resistivity
Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-237310
Classification DDC: 600 Technology, medicine, applied sciences > 620 Engineering and machine engineering
600 Technology, medicine, applied sciences > 660 Chemical engineering
Divisions: 11 Department of Materials and Earth Sciences > Material Science > Joint Research Laboratory Nanomaterials
Date Deposited: 28 Apr 2023 12:55
Last Modified: 14 Nov 2023 19:05
SWORD Depositor: Deep Green
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/23731
PPN: 509801269
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