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High temperature creep‐mediated functionality in polycrystalline barium titanate

Ren, Pengrong ; Höfling, Marion ; Koruza, Jurij ; Lauterbach, Stefan ; Jiang, Xijie ; Frömling, Till ; Khatua, Dipak Kumar ; Dietz, Christian ; Porz, Lukas ; Ranjan, Rajeev ; Kleebe, Hans‐Joachim ; Rödel, Jürgen (2023)
High temperature creep‐mediated functionality in polycrystalline barium titanate.
In: Journal of the American Ceramic Society, 2019, 103 (3)
doi: 10.26083/tuprints-00023203
Article, Secondary publication, Publisher's Version

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Item Type: Article
Type of entry: Secondary publication
Title: High temperature creep‐mediated functionality in polycrystalline barium titanate
Language: English
Date: 2023
Place of Publication: Darmstadt
Year of primary publication: 2019
Publisher: Wiley
Journal or Publication Title: Journal of the American Ceramic Society
Volume of the journal: 103
Issue Number: 3
DOI: 10.26083/tuprints-00023203
Corresponding Links:
Origin: Secondary publication service
Abstract:

Dislocations in oxides can be described as charged line defects and means for one-dimensional doping, which can tune electrical and thermal properties. Furthermore, theoretically it was shown that dislocations can pin ferroelectric domain walls. Broader application of this concept hinges on the development of a methodology to avail this approach to polycrystalline ceramics. To this end, we use different creep mechanisms as a method to introduce multidimensional defects and quantify structural changes. A deformation map for fine-grained barium titanate is provided and the influences of the defects and creep regimes are correlated in this first study to modifications of electrical conductivity, dielectric, ferroelectric, and piezoelectric properties. A plastic deformation of 1.29% resulted in an increase in the Curie temperature by 5°C and a decrease in electromechanical strain by 30%, pointing toward electromechanical hardening by dislocations.

Uncontrolled Keywords: barium titanate, creep, dislocations, ferroelectricity/ferroelectric materials, piezoelectric materials/ properties
Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-232035
Classification DDC: 500 Science and mathematics > 530 Physics
500 Science and mathematics > 540 Chemistry
Divisions: 11 Department of Materials and Earth Sciences > Material Science > Nonmetallic-Inorganic Materials
11 Department of Materials and Earth Sciences > Material Science > Physics of Surfaces
Date Deposited: 10 Feb 2023 09:26
Last Modified: 25 May 2023 06:13
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/23203
PPN: 507931386
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