Hafner, Klaus ; Stowasser, Bernd ; Krimmer, Hans-Peter ; Fischer, Stefanie ; Böhm, Michael C. ; Lindner, Hans Jörg (2023)
Synthesis and Properties of 1,3,5,7-Tetra-tert-butyl-s-indacene.
In: Angewandte Chemie International Edition, 1986, 25 (7)
doi: 10.26083/tuprints-00022361
Article, Secondary publication, Publisher's Version
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Angew Chem Int Ed Engl - July 1986 - Hafner - Synthesis and Properties of 1 3 5 7‐Tetra‐tert‐butyl‐s‐indacene.pdf Copyright Information: In Copyright. Download (921kB) |
| Item Type: | Article |
|---|---|
| Type of entry: | Secondary publication |
| Title: | Synthesis and Properties of 1,3,5,7-Tetra-tert-butyl-s-indacene |
| Language: | English |
| Date: | 2023 |
| Place of Publication: | Darmstadt |
| Year of primary publication: | 1986 |
| Publisher: | Wiley |
| Journal or Publication Title: | Angewandte Chemie International Edition |
| Volume of the journal: | 25 |
| Issue Number: | 7 |
| DOI: | 10.26083/tuprints-00022361 |
| Corresponding Links: | |
| Origin: | Secondary publication service |
| Abstract: | To check the influence of substituents on the bonding of the 12π-perimeter of s-indacene, a tetraalkyl derivative, the title compound 1, was synthesized. 1, red needles, is weakly paratropic. Crystal structure analysis and NMR investigations indicate a delocalized or a localized π-electron system with only a small energy barrier between the π-bond isomers. |
| Status: | Publisher's Version |
| URN: | urn:nbn:de:tuda-tuprints-223619 |
| Classification DDC: | 500 Science and mathematics > 540 Chemistry |
| Divisions: | 07 Department of Chemistry > Clemens-Schöpf-Institut > Organ Chemistry |
| Date Deposited: | 28 Feb 2023 08:53 |
| Last Modified: | 18 Aug 2023 06:34 |
| URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/22361 |
| PPN: | 510686729 |
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