Hafner, Klaus ; Knaup, Günter L. ; Lindner, Hans Jörg ; Flöter, Hans-Christian (2023)
Synthesis and Dynamic Properties of Chiral Heptalenes.
In: Angewandte Chemie International Edition, 1985, 24 (3)
doi: 10.26083/tuprints-00022359
Article, Secondary publication, Publisher's Version
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Angew Chem Int Ed Engl - March 1985 - Hafner - Synthesis and Dynamic Properties of Chiral Heptalenes.pdf Copyright Information: In Copyright. Download (917kB) |
| Item Type: | Article |
|---|---|
| Type of entry: | Secondary publication |
| Title: | Synthesis and Dynamic Properties of Chiral Heptalenes |
| Language: | English |
| Date: | 2023 |
| Place of Publication: | Darmstadt |
| Year of primary publication: | 1985 |
| Publisher: | Wiley |
| Journal or Publication Title: | Angewandte Chemie International Edition |
| Volume of the journal: | 24 |
| Issue Number: | 3 |
| DOI: | 10.26083/tuprints-00022359 |
| Corresponding Links: | |
| Origin: | Secondary publication service |
| Abstract: | The enantiomerically pure valence isomers (+)- and (−)-1 and (+)- and (-)-2 are the first of their kind to be isolated. These compounds, which have nonplanar, cyclic conjugated π-electron systems and localized π-bonds in the ground state, are in dynamic equilibrium with one another. The kinetic data for the dynamic processes–ring inversion and bond shift–were also determined (R = H, Me). |
| Status: | Publisher's Version |
| URN: | urn:nbn:de:tuda-tuprints-223590 |
| Classification DDC: | 500 Science and mathematics > 540 Chemistry |
| Divisions: | 07 Department of Chemistry > Clemens-Schöpf-Institut > Organ Chemistry |
| Date Deposited: | 30 Jan 2023 11:30 |
| Last Modified: | 21 Apr 2023 11:29 |
| URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/22359 |
| PPN: | 507136632 |
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