Bickert, Peter ; Boekelheide, Virgil ; Hafner, Klaus (2022)
Phanes Derived from 1, 5- and 1, 7-Dihydro-s-indacene.
In: Angewandte Chemie International Edition, 2022, 21 (4)
doi: 10.26083/tuprints-00022354
Article, Secondary publication, Publisher's Version
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Angew Chem Int Ed Engl - April 1982 - Bickert - Phanes Derived from 1 5‐ and 1 7‐Dihydro‐s‐indacene.pdf Copyright Information: In Copyright. Download (692kB) |
| Item Type: | Article |
|---|---|
| Type of entry: | Secondary publication |
| Title: | Phanes Derived from 1, 5- and 1, 7-Dihydro-s-indacene |
| Language: | English |
| Date: | 2022 |
| Place of Publication: | Darmstadt |
| Year of primary publication: | 2022 |
| Publisher: | Wiley |
| Journal or Publication Title: | Angewandte Chemie International Edition |
| Volume of the journal: | 21 |
| Issue Number: | 4 |
| DOI: | 10.26083/tuprints-00022354 |
| Corresponding Links: | |
| Origin: | Secondary publication service |
| Abstract: | Frontier orbital analysis of two conjugated, cyclic polyenes held face-to-face in close proximity suggests that when both polyenes have 4nπ-electron systems the interaction will be stabilizing, whereas when both have (4n+2)π-electron systems the interaction will be destabilizing[¹]. To test this prediction experimentally it would be of especial interest to examine phanes having nonbenzenoid aromatic and also antiaromatic decks as model compounds. |
| Status: | Publisher's Version |
| URN: | urn:nbn:de:tuda-tuprints-223543 |
| Additional Information: | German version: 10.26083/tuprints-00022247 |
| Classification DDC: | 500 Science and mathematics > 540 Chemistry |
| Divisions: | 07 Department of Chemistry > Clemens-Schöpf-Institut > Organ Chemistry |
| Date Deposited: | 22 Nov 2022 10:01 |
| Last Modified: | 21 Apr 2023 11:19 |
| URI: | https://tuprints.ulb.tu-darmstadt.de/id/eprint/22354 |
| PPN: | 507135911 |
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