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Synthesis and Rearrangement of Azulenesulfonium Salts

Müller, Manfred ; Braun, Siegmar ; Hafner, Klaus (2023)
Synthesis and Rearrangement of Azulenesulfonium Salts.
In: Angewandte Chemie International Edition, 1980, 19 (8)
doi: 10.26083/tuprints-00022353
Article, Secondary publication, Publisher's Version

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Item Type: Article
Type of entry: Secondary publication
Title: Synthesis and Rearrangement of Azulenesulfonium Salts
Language: English
Date: 2023
Place of Publication: Darmstadt
Year of primary publication: 1980
Publisher: Wiley
Journal or Publication Title: Angewandte Chemie International Edition
Volume of the journal: 19
Issue Number: 8
DOI: 10.26083/tuprints-00022353
Corresponding Links:
Origin: Secondary publication service
Abstract:

4-Functionalized azulenes have become accessible via the sulfonium salt (1), X = SMe₂⁺BF₄⁻. On rearrangement of this salt to (3) the dihydro derivative (2) can be isolated, whose formation is of interest in connection with the Sommelet rearrangement.

Status: Publisher's Version
URN: urn:nbn:de:tuda-tuprints-223533
Classification DDC: 500 Science and mathematics > 540 Chemistry
Divisions: 07 Department of Chemistry > Clemens-Schöpf-Institut > Organ Chemistry
Date Deposited: 21 Mar 2023 10:25
Last Modified: 18 Aug 2023 06:30
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/22353
PPN: 510686451
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