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Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors

Grätz, Sven ; Zink, Sebastian ; Kraffczyk, Hanna ; Rose, Marcus ; Borchardt, Lars (2021):
Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors. (Publisher's Version)
In: Beilstein Journal of Organic Chemistry, 15, pp. 1154-1161. Beilstein-Institut zur Förderung der Chemischen Wissenschaften, ISSN 1860-5397,
DOI: 10.26083/tuprints-00019905,
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Item Type: Article
Origin: Secondary publication service
Status: Publisher's Version
Title: Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors
Language: English
Abstract:

This study elucidates a mechanochemical polymerization reaction towards a hyper-crosslinked polymer as an alternative to conventional solvent-based procedures. The swift and solvent-free Friedel–Crafts alkylation reaction yields a porous polymer with surface areas of up to 1720 m2g −1 and pore volumes of up to 1.55 cm3g −1. The application of LAG (liquid-assisted grinding) revealed a profound impact of the liquid´s boiling point on the textural properties of the obtained polymer materials. Finally, the materials are characterized by vapour sorption experiments with benzene and cyclohexane.

Journal or Publication Title: Beilstein Journal of Organic Chemistry
Journal volume: 15
Publisher: Beilstein-Institut zur Förderung der Chemischen Wissenschaften
Classification DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
Divisions: 07 Department of Chemistry > Fachgebiet Technische Chemie > Technische Chemie II
Date Deposited: 18 Nov 2021 10:47
Last Modified: 18 Nov 2021 10:47
DOI: 10.26083/tuprints-00019905
Corresponding Links:
URN: urn:nbn:de:tuda-tuprints-199053
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/19905
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