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Surface Enhanced DNP Assisted Solid-State NMR of Functionalized SiO2 Coated Polycarbonate Membranes

Kumari, Bharti ; John, Daniel ; Hoffmann, Paul ; Spende, Anne ; Toimil-Molares, Maria Eugenia ; Trautmann, Christina ; Hess, Christian ; Ruff, Philip ; Schulze, Marcus ; Stark, Robert ; Buntkowsky, Gerd ; Andrieu-Brunsen, Annette ; Gutmann, Torsten (2021):
Surface Enhanced DNP Assisted Solid-State NMR of Functionalized SiO2 Coated Polycarbonate Membranes. (Publisher's Version)
In: Zeitschrift für Physikalische Chemie, 232 (7-8), pp. 1173-1186. De Gruyter, ISSN 0942-9352, e-ISSN 2196-7156,
DOI: 10.26083/tuprints-00019680,
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Item Type: Article
Origin: Secondary publication service
Status: Publisher's Version
Title: Surface Enhanced DNP Assisted Solid-State NMR of Functionalized SiO2 Coated Polycarbonate Membranes
Language: English
Abstract:

Surface enhanced solid-state NMR by dynamic nuclear polarization (DNP SENS) enables the characterization of the inner-pore surface functionalization of porous etched ion-track membranes exhibiting low specific surface areas compared to typical SBA- or MCM-type mesoporous silica materials. The membranes were conformally coated with a 5 nm thin SiO2 layer by atomic layer deposition. This layer was subsequently modified by aminopropyl silane linkers that allow further functionalization via the terminal amine group. The results evidence that in principle DNP SENS is a capable tool to analyze more complex porous systems, e.g. bioinspired functional etched ion-track membranes down to the molecular level. These results are relevant also for single nanopore systems, for which a direct analysis of the channel surface functionalization is not feasible by classical characterization methods. The applicability of DNP SENS to complex porous systems requires the optimization of the sample preparation and measurement parameters.

Journal or Publication Title: Zeitschrift für Physikalische Chemie
Journal volume: 232
Number: 7-8
Publisher: De Gruyter
Classification DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
Divisions: 07 Department of Chemistry > Physical Chemistry
Date Deposited: 01 Oct 2021 11:21
Last Modified: 01 Oct 2021 11:21
DOI: 10.26083/tuprints-00019680
Corresponding Links:
URN: urn:nbn:de:tuda-tuprints-196801
Additional Information:

Keywords: dynamic nuclear polarization; etched ion-track membranes; silica coating; solid-state NMR; surface analysis

URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/19680
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