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Interaction of Different Charged Polymers with Potassium Ions and Their Effect on the Yield Stress of Highly Concentrated Glass Bead Suspensions

Lu, Zichen ; Becker, Simon ; Leinitz, Sarah ; Schmidt, Wolfram ; Klitzing, Regine von ; Stephan, Dietmar (2021):
Interaction of Different Charged Polymers with Potassium Ions and Their Effect on the Yield Stress of Highly Concentrated Glass Bead Suspensions. (Publisher's Version)
In: Materials, 13 (7), MDPI, e-ISSN 1996-1944,
DOI: 10.26083/tuprints-00019048,
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Item Type: Article
Origin: Secondary publication service
Status: Publisher's Version
Title: Interaction of Different Charged Polymers with Potassium Ions and Their Effect on the Yield Stress of Highly Concentrated Glass Bead Suspensions
Language: English
Abstract:

The interaction of different charged polymers, namely anionic polycarboxylate superplasticizer (PCE) and neutral polyethylene glycol (PEG) with potassium ions, and their effect on the yield stress of highly concentrated glass bead suspension (GBS), were studied under different concentrations of potassium ions ([K⁺]). It was found that, compared to the neutral PEG, the negatively charged PCE can be adsorbed on glass beads (GB), and then decreases the yield stress of GBS. The increasing concentration of free polymer in the interstitial liquid phase with the increased polymer dosage leads to the higher yield stress of GBS, which may be caused by the higher depletion force. In addition, this effect is also related to the charge density of the polymer and the [K⁺] in the solution. Along with the increase in [K⁺], the yield stress of GBS increases significantly with the addition of PCE, but this cannot be observed with PEG, which indicates that potassium ions can interact with negatively charged PCE instead of the neutral PEG. At last, the interparticle forces between two single GB with adsorbed PCE in solutions containing [K⁺] and PCE were measured by colloidal probe atomic force microscopy to better understand the interaction of the charged polymer with counterions.

Journal or Publication Title: Materials
Journal volume: 13
Number: 7
Publisher: MDPI
Collation: 16 Seiten
Classification DDC: 500 Naturwissenschaften und Mathematik > 530 Physik
Divisions: 05 Department of Physics > Institute for Condensed Matter Physics
Date Deposited: 11 Aug 2021 13:00
Last Modified: 11 Aug 2021 13:00
DOI: 10.26083/tuprints-00019048
Corresponding Links:
URN: urn:nbn:de:tuda-tuprints-190483
URI: https://tuprints.ulb.tu-darmstadt.de/id/eprint/19048
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